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- W2034681715 abstract "Asymmetric synthesis of trans- and cis-2-Benzamido- or 2-Phenyl-acet-amido-cyclohexane-amines 7 and 8 by means of reductive amination and hydrogenolysis is described. Condensation of the amido-ketones 3 with chiral auxiliary (R)-(+) and (S)-(-)-1-phenylethylamine, respectively, leads to the amido-imines 4, which are hydrogenated over Raney-Ni to yield simultaneously enantiomerically pure secondary trans- and cis-2-amidocyclohexane-amines 5 and 6.Asymmetrische, reduktive Aminierung von Cycloalkanonen, 13. Mitt.: Enantioselektive Amidoaminierung: Eine neue regiospezifische Strategie zur Synthese von chiralen Cyclohexan-1,2-diamino-DerivatenDie asymmetrische Synthese von trans- und cis-2-Benzamido- oder -2-Phenylacetamido-cyclohexanaminen 7 und 8 mittels reduktiver Aminierung und Hydrogenolyse wird beschrieben. Die Kondensation der Amidoketone 3 mit den chiralen Hilfsaminen (R)-(+)- oder (S)-(-)-1-Phenylethylamin fuhrt zu den Amido-iminen 4, die sich mit Raney-Nickel zu den enantiomerenreinen sekundaren trans- und cis-2-Amido-cyclohexanaminen 5 und 6 hydrieren lassen." @default.
- W2034681715 created "2016-06-24" @default.
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- W2034681715 date "1993-01-01" @default.
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- W2034681715 title "Asymmetric Reductive Amination of Cycloalkanones, XIII: Enantioselective Amidoamination: A New Regiospecific Strategy for the Synthesis of Chiral Cyclohexane-1,2-diamino-Derivatives" @default.
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- W2034681715 doi "https://doi.org/10.1002/ardp.19933260711" @default.
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