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- W2034681929 abstract "In this communication are presented exact quantum mechanical nonadiabatic electronic transition probabilities for the collinear reaction Ar+ + H2(vi = 0) → ArH+(vf) + H. The calculations were performed using a potential surface calculated by the DIM method. It is established that large probabilities (≈ 1.0) can be obtained only if there is enough translational energy to overcome a potential barrier formed due to the crossing between vi = 0 of the Ar+ + H2 system and vi = 2 of the Ar + H+2 system. The threshold for the reaction is found to be 0.06 eV." @default.
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- W2034681929 date "1977-10-01" @default.
- W2034681929 modified "2023-10-14" @default.
- W2034681929 title "Electronic nonadiabatic transitions in the reactive (Ar+ + H2, Ar + H+2, ArH+ + H) system. Numerical results for the collinear configuration" @default.
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- W2034681929 doi "https://doi.org/10.1016/0009-2614(77)80421-1" @default.
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