Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034682279> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2034682279 endingPage "1665" @default.
- W2034682279 startingPage "1665" @default.
- W2034682279 abstract "3′,3′-Dimethyl-(3R)-spiro[A-norcholestane-3,2′-oxiran](1) and its 3S-isomer (2) give, on treatment with boron trifluoride–ether, acetone and A-norcholest-3(5)-ene (11). The oxetan (10). formed together with the allylic alcohol (9) during the chromatographic separation over alumina of (1) and (2), shows a similar behaviour, when submitted to the action of the same reagent. Similar treatment of 3-(1-deuterio-1-methylethyl)-3,5β-epoxy-A norcholestane (15) leads to acetone and 3-deuterio-A-norcholest-3(5)-ene (12). These results suggest a mechanism for all fragmentation reactions involving an oxetan intermediate such as (10)." @default.
- W2034682279 created "2016-06-24" @default.
- W2034682279 creator A5023524116 @default.
- W2034682279 creator A5045597026 @default.
- W2034682279 creator A5070391245 @default.
- W2034682279 creator A5076239598 @default.
- W2034682279 creator A5085879012 @default.
- W2034682279 date "1979-01-01" @default.
- W2034682279 modified "2023-09-23" @default.
- W2034682279 title "Boron trifluoride-catalysed rearrangements of some tetrasubstituted A-norcholestane epoxides. Evidence for the formation of an oxetan intermediate in a novel fragmentation reaction" @default.
- W2034682279 doi "https://doi.org/10.1039/p19790001665" @default.
- W2034682279 hasPublicationYear "1979" @default.
- W2034682279 type Work @default.
- W2034682279 sameAs 2034682279 @default.
- W2034682279 citedByCount "2" @default.
- W2034682279 crossrefType "journal-article" @default.
- W2034682279 hasAuthorship W2034682279A5023524116 @default.
- W2034682279 hasAuthorship W2034682279A5045597026 @default.
- W2034682279 hasAuthorship W2034682279A5070391245 @default.
- W2034682279 hasAuthorship W2034682279A5076239598 @default.
- W2034682279 hasAuthorship W2034682279A5085879012 @default.
- W2034682279 hasConcept C111919701 @default.
- W2034682279 hasConcept C120095180 @default.
- W2034682279 hasConcept C155647269 @default.
- W2034682279 hasConcept C161790260 @default.
- W2034682279 hasConcept C178790620 @default.
- W2034682279 hasConcept C185592680 @default.
- W2034682279 hasConcept C191015642 @default.
- W2034682279 hasConcept C2776468994 @default.
- W2034682279 hasConcept C2780407432 @default.
- W2034682279 hasConcept C2781213060 @default.
- W2034682279 hasConcept C40875361 @default.
- W2034682279 hasConcept C41008148 @default.
- W2034682279 hasConcept C501308230 @default.
- W2034682279 hasConceptScore W2034682279C111919701 @default.
- W2034682279 hasConceptScore W2034682279C120095180 @default.
- W2034682279 hasConceptScore W2034682279C155647269 @default.
- W2034682279 hasConceptScore W2034682279C161790260 @default.
- W2034682279 hasConceptScore W2034682279C178790620 @default.
- W2034682279 hasConceptScore W2034682279C185592680 @default.
- W2034682279 hasConceptScore W2034682279C191015642 @default.
- W2034682279 hasConceptScore W2034682279C2776468994 @default.
- W2034682279 hasConceptScore W2034682279C2780407432 @default.
- W2034682279 hasConceptScore W2034682279C2781213060 @default.
- W2034682279 hasConceptScore W2034682279C40875361 @default.
- W2034682279 hasConceptScore W2034682279C41008148 @default.
- W2034682279 hasConceptScore W2034682279C501308230 @default.
- W2034682279 hasLocation W20346822791 @default.
- W2034682279 hasOpenAccess W2034682279 @default.
- W2034682279 hasPrimaryLocation W20346822791 @default.
- W2034682279 hasRelatedWork W1963823630 @default.
- W2034682279 hasRelatedWork W1970280741 @default.
- W2034682279 hasRelatedWork W1991627413 @default.
- W2034682279 hasRelatedWork W2027782016 @default.
- W2034682279 hasRelatedWork W2034604682 @default.
- W2034682279 hasRelatedWork W2043256912 @default.
- W2034682279 hasRelatedWork W2093796341 @default.
- W2034682279 hasRelatedWork W2696358862 @default.
- W2034682279 hasRelatedWork W2949183583 @default.
- W2034682279 hasRelatedWork W2953155228 @default.
- W2034682279 isParatext "false" @default.
- W2034682279 isRetracted "false" @default.
- W2034682279 magId "2034682279" @default.
- W2034682279 workType "article" @default.