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- W2034683154 abstract "At pH 9.5, 40°, ethyl acetate simultaneously undergoes hydrolysis and hydroxyaminolysis to yield acetic acid and acetohydroxamic acid (N-hydroxyacetamide), respectively. The pseudo first-order rate constants for the overall reaction have been calculated from data based on the colorimetric determination of the hydroxamic acid-iron complex and by the pH-stat method. Yields of both products have been determined. Both O- and N-attack by NH2OH on ethyl acetate has been postulated to explain the observed reaction yields. In the case of the O-attack the resulting O-acetylhydroxylamine is a reactive intermediate which undergoes further hydrolysis and hydroxyaminolysis to yield acetic acid and acetohydroxamic acid, respectively." @default.
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- W2034683154 date "1969-09-01" @default.
- W2034683154 modified "2023-09-26" @default.
- W2034683154 title "Hydroxamic acids III: Kinetics of acetohydroxamic acid formation from ethyl acetate" @default.
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- W2034683154 doi "https://doi.org/10.1002/jps.2600580906" @default.
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