FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034690728> ?p ?o ?g. }

• W2034690728 endingPage "13731" @default.
• W2034690728 startingPage "13723" @default.
• W2034690728 abstract "Nylon 6,6 thin films have been examined by Raman spectroscopy to determine how chain conformation is influenced by environmental parameters such as exposure to water and temperature variations. The motivation for this work is to elucidate how interactions between water and the model polymers mediate polymer structures in applications such as the removal of salt from water in reverse osmosis membranes. Raman spectra show that model self-assembled monolayers containing Nylon 6,6 chains are semicrystalline under ambient conditions. The native chains adopt an unusual kinked and folded conformation related to that found in γ-Nylon 6,6. The regular chain deformations allow adjacent tethered chains to maximize hydrogen-bonding between neighboring amide groups under the constraints imposed by surface tethering. With increasing temperature, the films undergo a phase transition associated with the disruption of hydrogen bonds leading to structures containing more linear regions that are closer to the “all trans” case. Similar structural changes are observed on exposing the Nylon films to water. The salt content of the water does not appear to have a significant impact on the structure or phase transition in the Nylon 6,6. These results suggest that while inclusion of water has a profound effect on the polymer structure, either salt is excluded from the polymer or there is sufficient free volume within the films to accommodate hydrated ions without inducing further structural changes." @default.
• W2034690728 created "2016-06-24" @default.
• W2034690728 creator A5003420811 @default.
• W2034690728 creator A5015111176 @default.
• W2034690728 creator A5015544419 @default.
• W2034690728 date "2009-07-13" @default.
• W2034690728 modified "2023-10-06" @default.
• W2034690728 title "Effects of Water and Temperature on Conformational Order in Model Nylon Thin Films" @default.
• W2034690728 cites W1963788008 @default.
• W2034690728 cites W1964074855 @default.
• W2034690728 cites W1975117221 @default.
• W2034690728 cites W1984988232 @default.
• W2034690728 cites W1986825046 @default.
• W2034690728 cites W1988211227 @default.
• W2034690728 cites W1990301493 @default.
• W2034690728 cites W1993593865 @default.
• W2034690728 cites W1993917151 @default.
• W2034690728 cites W1994197058 @default.
• W2034690728 cites W1994412504 @default.
• W2034690728 cites W2002581766 @default.
• W2034690728 cites W2008046073 @default.
• W2034690728 cites W2018120084 @default.
• W2034690728 cites W2018635812 @default.
• W2034690728 cites W2025763718 @default.
• W2034690728 cites W2027866197 @default.
• W2034690728 cites W2028028245 @default.
• W2034690728 cites W2031760917 @default.
• W2034690728 cites W2035402496 @default.
• W2034690728 cites W2036166126 @default.
• W2034690728 cites W2036452443 @default.
• W2034690728 cites W2039929826 @default.
• W2034690728 cites W2042343648 @default.
• W2034690728 cites W2045499447 @default.
• W2034690728 cites W2051350873 @default.
• W2034690728 cites W2053169023 @default.
• W2034690728 cites W2065917915 @default.
• W2034690728 cites W2066218098 @default.
• W2034690728 cites W2075390833 @default.
• W2034690728 cites W2088374197 @default.
• W2034690728 cites W2094636816 @default.
• W2034690728 cites W2164198199 @default.
• W2034690728 cites W4245485591 @default.
• W2034690728 doi "https://doi.org/10.1021/jp901309y" @default.
• W2034690728 hasPublicationYear "2009" @default.
• W2034690728 type Work @default.
• W2034690728 sameAs 2034690728 @default.
• W2034690728 citedByCount "19" @default.
• W2034690728 countsByYear W20346907282012 @default.
• W2034690728 countsByYear W20346907282013 @default.
• W2034690728 countsByYear W20346907282014 @default.
• W2034690728 countsByYear W20346907282015 @default.
• W2034690728 countsByYear W20346907282017 @default.
• W2034690728 countsByYear W20346907282018 @default.
• W2034690728 countsByYear W20346907282020 @default.
• W2034690728 countsByYear W20346907282022 @default.
• W2034690728 crossrefType "journal-article" @default.
• W2034690728 hasAuthorship W2034690728A5003420811 @default.
• W2034690728 hasAuthorship W2034690728A5015111176 @default.
• W2034690728 hasAuthorship W2034690728A5015544419 @default.
• W2034690728 hasConcept C112887158 @default.
• W2034690728 hasConcept C120665830 @default.
• W2034690728 hasConcept C121332964 @default.
• W2034690728 hasConcept C127413603 @default.
• W2034690728 hasConcept C149288129 @default.
• W2034690728 hasConcept C159467904 @default.
• W2034690728 hasConcept C171250308 @default.
• W2034690728 hasConcept C178790620 @default.
• W2034690728 hasConcept C185592680 @default.
• W2034690728 hasConcept C188027245 @default.
• W2034690728 hasConcept C190399342 @default.
• W2034690728 hasConcept C192562407 @default.
• W2034690728 hasConcept C204921945 @default.
• W2034690728 hasConcept C2776371256 @default.
• W2034690728 hasConcept C2781215361 @default.
• W2034690728 hasConcept C32909587 @default.
• W2034690728 hasConcept C40003534 @default.
• W2034690728 hasConcept C41625074 @default.
• W2034690728 hasConcept C42360764 @default.
• W2034690728 hasConcept C44280652 @default.
• W2034690728 hasConcept C46275449 @default.
• W2034690728 hasConcept C521977710 @default.
• W2034690728 hasConcept C55493867 @default.
• W2034690728 hasConcept C7070889 @default.
• W2034690728 hasConcept C8010536 @default.
• W2034690728 hasConcept C97355855 @default.
• W2034690728 hasConceptScore W2034690728C112887158 @default.
• W2034690728 hasConceptScore W2034690728C120665830 @default.
• W2034690728 hasConceptScore W2034690728C121332964 @default.
• W2034690728 hasConceptScore W2034690728C127413603 @default.
• W2034690728 hasConceptScore W2034690728C149288129 @default.
• W2034690728 hasConceptScore W2034690728C159467904 @default.
• W2034690728 hasConceptScore W2034690728C171250308 @default.
• W2034690728 hasConceptScore W2034690728C178790620 @default.
• W2034690728 hasConceptScore W2034690728C185592680 @default.
• W2034690728 hasConceptScore W2034690728C188027245 @default.
• W2034690728 hasConceptScore W2034690728C190399342 @default.
• W2034690728 hasConceptScore W2034690728C192562407 @default.
• W2034690728 hasConceptScore W2034690728C204921945 @default.

• next