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• W2034692712 abstract "Phase diagrams of [001] and [110] field-cooled (FC) $(1ensuremath{-}x)mathrm{Pb}({mathrm{Mg}}_{1∕3}{mathrm{Nb}}_{2∕3}{mathrm{O}}_{3})text{ensuremath{-}}xmathrm{Pb}mathrm{Ti}{mathrm{O}}_{3}$ or PMN-$xmathrm{PT}$ $(0.15ensuremath{leqslant}xensuremath{leqslant}0.38)$ crystals have been constructed, based on high-resolution x-ray diffraction data. Comparisons reveal several interesting findings. First, a region of abnormal thermal expansion $(censuremath{ne}a)$ above the dielectric maximum was found, whose stability range extended to higher temperatures on application of electric field $(E)$. Second, the rhombohedral $(R)$ phase of the zero-field-cooled (ZFC) state was replaced by monoclinic ${M}_{A}$ in the [001] FC diagram, but with monoclinic ${M}_{B}$ in the [110] FC. Third, the monoclinic ${M}_{C}$ phase in the ZFC and [001] FC diagram was replaced by an orthorhombic $(O)$ phase in the [110] FC diagram. Finally, in the [001] FC diagram, the phase boundary between tetragonal $(T)$ and ${M}_{A}$ phases was extended to lower PT content $(x=0.25)$; whereas in the [110] FC diagram, this extended region was entirely replaced by the $O$ phase. These results clearly demonstrate that the phase stability of PMN-$xmathrm{PT}$ crystals is quite fragile---depending not only on modest changes in $E$, but also on the direction along which $E$ is applied." @default.
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• W2034692712 date "2006-05-09" @default.
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• W2034692712 title "Fragile phase stability in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mi mathvariant=normal>Pb</mml:mi><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant=normal>Mg</mml:mi><mml:mrow><mml:mn>1</mml:mn><mml:mo>∕</mml:mo><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mi mathvariant=normal>Nb</mml:mi><mml:mrow><mml:mn>2</mml…" @default.
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• W2034692712 doi "https://doi.org/10.1103/physrevb.73.184110" @default.
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