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- W2034693410 abstract "The electron-cloud distortion of GaAs and ZnSe under uniaxial stress is discussed using the Chadi-Cohen empirical linear-combination-of-atomic-orbitals band theory. The electron localizability $ensuremath{lambda}=frac{({a}^{2}ensuremath{-}{b}^{2})}{({a}^{2}+{b}^{2})}$, where $a$ is the weight of the anion atomic wave function and $b$ is that of the cation atomic wave function in the valence-state wave function ${ensuremath{psi}}_{v}=a{ensuremath{psi}}^{ensuremath{alpha}}+b{ensuremath{psi}}^{ensuremath{beta}}$, changes with the bond bending of the tetrahedral structure induced by [111]-directional external stress. This electron redistribution effect gives a large contribution to the piezoelectric constant. $frac{{e}_{b}^{*}}{{e}_{0}}$ is 0.32 for GaAs and 0.27 for ZnSe, ${e}_{b}^{*}$ being the effective charge due to the bond-bending effect." @default.
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- W2034693410 date "1978-10-15" @default.
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- W2034693410 title "Contribution of the electron redistribution effect to the piezoelectric constant due to the bond bending in tetrahedral crystals" @default.
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- W2034693410 doi "https://doi.org/10.1103/physrevb.18.4426" @default.
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