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- W2034695930 abstract "Reactions of alkynes with [MoSC6F5(CF3CCCF3)2(η5-C5H5)]1 gives the novel proneη4-butadienyl complex [Mo{η4-C(CF3)C(CF3)C(R′)C(R)(SC6F5)}(CF3CCCF3)(η5-C5H5)], which undergoes isomerisation via an η2-vinyl intermediate to the supine isomer followed by a novel 1,4-thiolate migration to give supine-[Mo{η4-C(CF3)(SC6F5)C(CF3)C(R)C(R′)}(CF3CCF3)(η5-C5H5)]." @default.
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- W2034695930 date "1990-01-01" @default.
- W2034695930 modified "2023-09-25" @default.
- W2034695930 title "Molybdenum promoted alkyne dimerisation leading to novel metallacycles: the crystal and molecular structures of prone-[Mo{η4-C(CF3)C(CF3)C(Me)C(CO2Me)(SC6F5)}(CF3CCCF3)(η5-C5H5)] and supine-[Mo{η4-C(CF3)(SC6F5)C(CF3)C(Ph)C(Ph)}-(CF3CCCF3)(η5-C5H5)]" @default.
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- W2034695930 doi "https://doi.org/10.1039/c39900001399" @default.
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