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- W2034698483 abstract "A flexible and practical protocol for the asymmetric synthesis of renieramycin-type antitumor alkaloids is described, in which the stereoselective Pictet–Spengler cyclization of amino ester 16 and aldehyde 15 by regulating temperature and the automatic lactamization after N-deprotection of the cyclization product are exploited to rapidly construct the common pentacyclic framework. (–)-Renieramycin G and (–)-jorunnamycin A, as representative members of the two subgroup renieramycin-type alkaloids, are obtained in 19 steps from L-tyrosine with 15.8% and 14.3% overall yield respectively." @default.
- W2034698483 created "2016-06-24" @default.
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- W2034698483 date "2014-01-01" @default.
- W2034698483 modified "2023-10-15" @default.
- W2034698483 title "A rapid and efficient access to renieramycin-type alkaloids featuring a temperature-dependent stereoselective cyclization" @default.
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- W2034698483 doi "https://doi.org/10.1039/c3ob42209g" @default.
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