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- W2034698771 abstract "Infrared spectra of H2O- andD2O-NaAlSi3O8 (albite) glasses were measured and contain two major differences from the anhydrous glass spectra. The first is the presence of a number of bands above 3000 cm−1 arising from O-H stretching modes. The second change in hydrous glass spectra is the appearance of a shoulder at approximately 900 cm−1. No frequency shift of the 900 cm−1 shoulder was detected with H-D substitution. We conclude, based on our infrared spectra and molecular orbital calculations as well as previous NMR (Kohn et al., 1989) and Raman (Mysen and Virgo, 1986a) spectra, that the 900 cm−1 band in the vibrational spectra of H2O-albite glass arises from an Al-(OH) stretching vibration in an Al Q3 site. The model proposed in this paper is that below 30 mol% [H2O]tot, molecular water interacts with the network A13+ to produce Al-(OH) and a minor concentration of Si-(OH) bonds. Above 30 mol% [H2O]tot, the dominant species is molecular H2O and H+ exchanges with Na+ at the charge-balancing site to produce molecular NaOH or hydrated Na+(H2O)n, complexes in the melt." @default.
- W2034698771 created "2016-06-24" @default.
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- W2034698771 date "1993-03-01" @default.
- W2034698771 modified "2023-10-04" @default.
- W2034698771 title "A model for H2O solubility mechanisms in albite melts from infrared spectroscopy and molecular orbital calculations" @default.
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- W2034698771 doi "https://doi.org/10.1016/0016-7037(93)90039-y" @default.
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