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• W2034701897 abstract "The dinuclear Zn2+ complex [Zn(HSSC)OAc]2·2DMF (H2SSC = salicylaldehyde semicarbazone; HOAc = acetic acid; DMF = N,N-dimethylfomamide) was prepared and structurally characterized by single crystal X-ray. The basic structural unit of the complex is a dinuclear complex [Zn(HSSC)OAc]2 in which the semicarbazone ligand adopts the phenol-imine form. The deprotonated phenol group forms a one-atom bridge between the two zinc centers, and both of the zinc centers are five-coordinated. The local coordination environment of Zn2+ can be approximately considered as square pyramidal. UV spectral studies show that the H2SSC provides strong binding of Zn2+ in a 1:1 ratio in solution. The conditional binding constant of the complex is lg KZn–L = 12.89 ± 0.76 in 0.05 M Tris–HCl buffer at pH 7.4. The H2SSC exhibits an enhanced fluorescence effect by the addition of Zn2+, and affords an excellent selectivity for Zn2+ under physiological conditions." @default.
• W2034701897 created "2016-06-24" @default.
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• W2034701897 date "2011-04-01" @default.
• W2034701897 modified "2023-09-26" @default.
• W2034701897 title "Structure and spectral properties of dinuclear zinc complex containing semicarbazonate ligands" @default.
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• W2034701897 doi "https://doi.org/10.1016/j.saa.2010.12.029" @default.
• W2034701897 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21288765" @default.
• W2034701897 hasPublicationYear "2011" @default.
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