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- W2034706873 abstract "This review summarises recent work from several groups on the preparation and photophysical properties of d–f heteronuclear assemblies in which a strongly light absorbing d-block chromophore is used as an antenna group to generate sensitised luminescence from near-infrared emitting lanthanide(III) centres (especially Yb, Nd, Er) following d → f photoinduced energy-transfer. An introduction summarises the technological importance of near-IR luminescence, the problems associated with its sensitisation and the resultant short lifetimes, and how these might be overcome. The next section describes work in this field from other groups; the last reviews work from the authors own group on (i) polypyridine-bridged d–f complexes and (ii) cyanide-bridged d–f coordination networks, with an emphases on both molecular design and synthesis, and understanding the photophysical properties such as the efficiency of d → f photoinduced energy-transfer." @default.
- W2034706873 created "2016-06-24" @default.
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- W2034706873 date "2007-07-01" @default.
- W2034706873 modified "2023-10-02" @default.
- W2034706873 title "Transition-metal sensitised near-infrared luminescence from lanthanides in d–f heteronuclear arrays" @default.
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- W2034706873 doi "https://doi.org/10.1016/j.ccr.2006.10.005" @default.
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