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- W2034709767 abstract "Abstract The chemical shift anisotropy and the spin-lattice relaxation rates in the laboratory and the rotating frame, respectively, of Te125 in tellurium single crystals have been measured between room temperature and the melting point (724K). The chemical shift anisotropy is shown to be independent of the temperature, whereas the whole spectrum scales with the temperature due to the Knight-shift in semiconductors. Below 420 K the relaxation rate is due to the relaxation via conducting electrons. Above 420 K the relaxation is caused by interstitialcy diffusion with an activation energy of about 0.6 eV. Near the melting point the relaxation due to translational atomic diffusion along the c-axis becomes dominant. The measured relaxation data can be explained by fluctuating anisotropic chemical shift interactions." @default.
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- W2034709767 title "Nuclear magnetic resonance in tellurium single crystals: Electron paramagnetism and atomic self-diffusion mechanisms" @default.
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