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- W2034721405 abstract "Aus dem kürzlich totalsynthetisch dargestellten Sesquiterpenketon (±)-Acorenon-B (1) wurde durch Wharton-Reaktion seines Epoxi-ketons 4 (±)-Acorenon (6) erhalten. Die stereochemische Korrelation von 1 mit 6 durch Konfigurationsinversion am Spirochiralitätszentrum C-5 stellt gleichzeitig die erste Synthese für 6 dar. The sesquiterpene ketone (±)-acorenone-B (1) formerly obtained by total synthesis was converted by Wharton reaction of its epoxy ketone 4 into (±)-acorenone (6). The stereochemical correlation of 1 with 6 by configurational inversion at the spirochirality center C-5 also represents the first synthesis of 6." @default.
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- W2034721405 date "1977-01-01" @default.
- W2034721405 modified "2023-10-16" @default.
- W2034721405 title "Synthese von spiroverbindungen—V" @default.
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- W2034721405 doi "https://doi.org/10.1016/s0040-4020(77)80018-5" @default.
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