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- W2034737071 abstract "We demonstrate that cyclooctatetraene (COT) can be stabilised in different conformations when adsorbed on different noble-metal surfaces due to varying molecule–substrate interactions. While at first glance the behaviour seems to be in accordance with Hückel's rule, a theoretical analysis reveals no significant charge transfer. The driving mechanism for the conformational change is hybridisation at the organic–metal interface and does not necessitate any charge transfer." @default.
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- W2034737071 date "2013-01-01" @default.
- W2034737071 modified "2023-09-27" @default.
- W2034737071 title "Hybridisation at the organic–metal interface: a surface-scientific analogue of Hückel's rule?" @default.
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- W2034737071 doi "https://doi.org/10.1039/c3cc42574f" @default.
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