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- W2034763376 abstract "A general differential technique is proposed for obtaining non-isothermal kinetic information from thermogravimetric data. This method uses a differential form of the general non-isothermal kinetic expression and fits desolvation data to rate laws corresponding to each of 11 solid-state mechanisms. The correct mechanism is determined to be the one the data fit most closely and the activation energy is calculated for this rate law. The method was used to evaluate the desolvation of six sulfonamide-ammonia adducts. A correlation was found between the calculated isothermal activation energies for a drug and its pKa. Sulfonamides with higher pKa values had lower desolvation activation energies and those with lower pKa values had higher desolvation activation energies." @default.
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- W2034763376 date "1992-02-01" @default.
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- W2034763376 title "Solid-state non-isothermal kinetics of sulfonamide-ammonia adduct desolvation" @default.
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- W2034763376 doi "https://doi.org/10.1016/0040-6031(92)80101-2" @default.
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