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- W2034763775 abstract "The photoreaction of the solution systems of 9-acridone (or N-methyl-9-acridone) and phenols was investigated by optical spectroscopy, ESR, and time-resolved CIDEP techniques. CIDEP signals of acridone semiquinone and phenoxyl radicals were detected together and the hyperfine coupling constants of acridone semiquinone were determined for the first time by simulation method. It was also clarified that radical pair mechanism (RPM) with triplet precursor and triplet mechanism (TM) were the main spin polarization mechanisms in these systems. The results indicate that the excited triplet state of acridone abstracts a hydrogen of phenols. Temperature, phenol concentration, light intensity and time dependence of the phenoxyl CIDEP signal intensity and/or pattern supported the conclusion." @default.
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- W2034763775 date "1993-06-01" @default.
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- W2034763775 title "CIDEP Study of Radicals Produced Photochemically in the Organic Solution of 9-Acridone and Phenols" @default.
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- W2034763775 doi "https://doi.org/10.1246/bcsj.66.1627" @default.
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