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- W2034767587 abstract "The fragmentation patterns of dialkylphosphinates show predominance of species corresponding to phosphinate molecular ions and phosphacylium ions. A preferred path of fragmentation appears to be alkylP → alkene + HP, with alkyl groups larger than Me. For example, in the spectrum of diethylphosphinic acid, the base peak corresponds to HPO2H+ presumably produced from the initially formed parent ion by loss of Et radical and ethylene. It thus appears possible to predict the modes of fragmentation of alkyl-P(V) compounds enabling mass spectrometry to be of considerable utility in structural analysis. The predominant species and pathways of fragmentation provide some interesting chemistry of energetic species." @default.
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- W2034767587 date "1968-01-01" @default.
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- W2034767587 title "A mass spectrometric study of some dialkylphosphinic acids and their alkyl esters" @default.
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- W2034767587 doi "https://doi.org/10.1016/0040-4020(68)88006-8" @default.
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