Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034768686> ?p ?o ?g. }
- W2034768686 endingPage "4461" @default.
- W2034768686 startingPage "4457" @default.
- W2034768686 abstract "The electronic absorption spectrum of the benzyl radical (C6H5CH2•) has been measured in the region of the vibrationally mixed 12A2−22B1 excited states near 450 nm by cavity ring-down spectroscopy (CRDS) in 20 Torr of argon or nitrogen diluents at 298 K. The absorption cross section was determined from the CRDS absorption and the rates of radical−radical cross reactions. At 447.7 nm, σbenzyl = (2.2 ± 0.8) × 10-18 cm2 molecule-1 (base e). The rate constant for the reaction of benzyl radicals with Cl atoms was derived during the modeling: k(C6H5CH2 + Cl) = (2.5 ± 1.0) × 10-10 cm3 molecule-1 s-1. Time-dependent density functional theory calculations support the interpretation of the absorption spectrum of the benzyl radical." @default.
- W2034768686 created "2016-06-24" @default.
- W2034768686 creator A5021135046 @default.
- W2034768686 creator A5039720740 @default.
- W2034768686 date "2003-05-06" @default.
- W2034768686 modified "2023-10-17" @default.
- W2034768686 title "Cavity Ring-Down Spectroscopy of the Benzyl Radical" @default.
- W2034768686 cites W1748197155 @default.
- W2034768686 cites W1964314183 @default.
- W2034768686 cites W1969106313 @default.
- W2034768686 cites W1970549136 @default.
- W2034768686 cites W1975598688 @default.
- W2034768686 cites W1979625452 @default.
- W2034768686 cites W1993077801 @default.
- W2034768686 cites W1995313530 @default.
- W2034768686 cites W1995740319 @default.
- W2034768686 cites W1996579676 @default.
- W2034768686 cites W1997667684 @default.
- W2034768686 cites W1997785740 @default.
- W2034768686 cites W2001303401 @default.
- W2034768686 cites W2001698276 @default.
- W2034768686 cites W2003271742 @default.
- W2034768686 cites W2007666980 @default.
- W2034768686 cites W2010245160 @default.
- W2034768686 cites W2017305668 @default.
- W2034768686 cites W2017793388 @default.
- W2034768686 cites W2023210706 @default.
- W2034768686 cites W2023271753 @default.
- W2034768686 cites W2032329469 @default.
- W2034768686 cites W2033051992 @default.
- W2034768686 cites W2034742574 @default.
- W2034768686 cites W2034954310 @default.
- W2034768686 cites W2045353095 @default.
- W2034768686 cites W2045581284 @default.
- W2034768686 cites W2052512054 @default.
- W2034768686 cites W2054875349 @default.
- W2034768686 cites W2057292758 @default.
- W2034768686 cites W2077679225 @default.
- W2034768686 cites W2080648424 @default.
- W2034768686 cites W2084998582 @default.
- W2034768686 cites W2085775450 @default.
- W2034768686 cites W2085779048 @default.
- W2034768686 cites W2086128189 @default.
- W2034768686 cites W2090343268 @default.
- W2034768686 cites W2093374055 @default.
- W2034768686 cites W2094562704 @default.
- W2034768686 cites W2107247898 @default.
- W2034768686 cites W2109362806 @default.
- W2034768686 cites W2114514241 @default.
- W2034768686 cites W2143981217 @default.
- W2034768686 cites W2152278650 @default.
- W2034768686 cites W2187439399 @default.
- W2034768686 cites W225987337 @default.
- W2034768686 cites W2325493762 @default.
- W2034768686 cites W2623010742 @default.
- W2034768686 cites W2950912565 @default.
- W2034768686 cites W4240035468 @default.
- W2034768686 doi "https://doi.org/10.1021/jp027280k" @default.
- W2034768686 hasPublicationYear "2003" @default.
- W2034768686 type Work @default.
- W2034768686 sameAs 2034768686 @default.
- W2034768686 citedByCount "23" @default.
- W2034768686 countsByYear W20347686862012 @default.
- W2034768686 countsByYear W20347686862014 @default.
- W2034768686 countsByYear W20347686862015 @default.
- W2034768686 countsByYear W20347686862017 @default.
- W2034768686 countsByYear W20347686862018 @default.
- W2034768686 countsByYear W20347686862019 @default.
- W2034768686 countsByYear W20347686862020 @default.
- W2034768686 countsByYear W20347686862021 @default.
- W2034768686 crossrefType "journal-article" @default.
- W2034768686 hasAuthorship W2034768686A5021135046 @default.
- W2034768686 hasAuthorship W2034768686A5039720740 @default.
- W2034768686 hasConcept C119824511 @default.
- W2034768686 hasConcept C121332964 @default.
- W2034768686 hasConcept C125287762 @default.
- W2034768686 hasConcept C139066938 @default.
- W2034768686 hasConcept C147597530 @default.
- W2034768686 hasConcept C148898269 @default.
- W2034768686 hasConcept C152365726 @default.
- W2034768686 hasConcept C155552310 @default.
- W2034768686 hasConcept C159985019 @default.
- W2034768686 hasConcept C175804951 @default.
- W2034768686 hasConcept C178790620 @default.
- W2034768686 hasConcept C181500209 @default.
- W2034768686 hasConcept C184779094 @default.
- W2034768686 hasConcept C185592680 @default.
- W2034768686 hasConcept C192562407 @default.
- W2034768686 hasConcept C2780378348 @default.
- W2034768686 hasConcept C30646810 @default.
- W2034768686 hasConcept C32891209 @default.
- W2034768686 hasConcept C32909587 @default.
- W2034768686 hasConcept C62520636 @default.
- W2034768686 hasConcept C75473681 @default.
- W2034768686 hasConcept C93391505 @default.
- W2034768686 hasConcept C97355855 @default.
- W2034768686 hasConceptScore W2034768686C119824511 @default.
- W2034768686 hasConceptScore W2034768686C121332964 @default.