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- W2034772458 abstract "Substantial improvements in amperometric monitoring of flowing streams are obtained by using Nafion-coated working electrodes. The charged coating tends to exclude anionic and neutral interferences, thus adding a new dimension of selectivity to electrochemical detection for flow-injection and liquid-chromatographic systems. A highly selective response is observed for cationic neurotransmitters in the presence of otherwise interfering substances (e.g., ascorbic acid, uric acid, bilirubin or chlorpromazine). The permselectivity and transport characteristics are evaluated with respect to solution pH, solvent, flow rate, film thickness, and other variables. The reduced flow-rate dependence results in low noise levels and detection limits of 0.04 and 0.10 ng of norepinephrine and epinephrine, respectively. A bilayer electrode coating, with a cellulose acetate film over the Nafion layer, offers a bifunctional (selectivity, protection) capability. Applicability to urine samples is demonstrated." @default.
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- W2034772458 date "1987-01-01" @default.
- W2034772458 modified "2023-09-24" @default.
- W2034772458 title "Amperometric detection of cationic neurotransmitters at nafion-coated glassy carbon electrodes in flow streams" @default.
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- W2034772458 doi "https://doi.org/10.1016/s0003-2670(00)84766-2" @default.
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