Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034773731> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2034773731 endingPage "1615" @default.
- W2034773731 startingPage "1609" @default.
- W2034773731 abstract "The reaction of [ReO(OEt)Cl2(PPh3)2] with N-(2-pyridylmethyl)-2-aminoethanol (mpenOH) afforded a mixture of ReV−oxo complexes, from which the dichloro complex [ReOCl2(mpenO-N,N‘,O)] (1) and the chlorotriphenylphosphine complex [ReOCl(PPh3)(mpenO-N,N‘,O)]PF6 (2) were isolated by addition of NH4PF6. Similarly, [ReO(OEt)Cl2(PPh3)2] reacted with N,N-bis(2-pyridylmethyl)-2-aminoethanol (bpenOH) to give the dichloro complex [ReOCl2(bpenO-N,N‘,O)] (3) and the monochloro complex [ReOCl(bpenO-N,N‘,N‘‘,O)]PF6 (4). When ethylene glycol (H2eg) was added to the mixture of [ReO(OEt)Cl2(PPh3)2] and bpenOH, [ReO(eg)(bpenOH-N,N‘,N‘‘)]ReO4 (5) was obtained. These five newly prepared complexes were structurally characterized. A mechanistic insight into the stepwise complex formation reaction of [ReO(OEt)Cl2(PPh3)2] with pyridylmethylamine derivatives (mpenOH and bpenOH) is discussed. Crystal data: [ReOCl2(mpenO)] (1), monoclinic, space group P21/c, a = 8.632(1) Å, b = 9.288(1) Å, c = 14.802(1) Å, β = 100.627(9)°, Z = 4; [ReOCl(PPh3)(mpenO)](PF6)·0.5CH3CN (2·0.5CH3CN), monoclinic, space group P21/a, a = 19.758(6) Å, b = 9.463(3) Å, c = 16.297(4) Å, β = 93.40(2)°, Z = 4; [ReOCl2(bpenO)] (3), monoclinic, space group P21, a = 6.577(1) Å, b = 13.269(2) Å, c = 9.686(2) Å, β = 105.00(2)°, Z = 2; [ReOCl(bpenO)](PF6) (4), triclinic, space group P1̄, a = 6.766(1) Å, b = 14.538(2) Å, c = 19.373(3) Å, α = 91.57(1)°, β = 97.43(1)°, γ = 91.62(1)°, Z = 4; [ReO(eg)(bpenOH)](ReO4) (5), monoclinic, space group P21/n, a = 12.691(2) Å, b = 14.030(2) Å, c = 11.153(2) Å, β = 90.72(1)°, Z = 4." @default.
- W2034773731 created "2016-06-24" @default.
- W2034773731 creator A5014383490 @default.
- W2034773731 creator A5047752377 @default.
- W2034773731 creator A5056552692 @default.
- W2034773731 creator A5086995669 @default.
- W2034773731 date "1998-03-03" @default.
- W2034773731 modified "2023-10-16" @default.
- W2034773731 title "Chelation Processes to an Oxorhenium(V) Center by N,N,N,O-Tetradentate and N,N,O-Tridentate Ligands As Verified by Structural and Mechanistic Studies of Intermediate Species" @default.
- W2034773731 cites W1969608944 @default.
- W2034773731 cites W1984407826 @default.
- W2034773731 cites W1995131074 @default.
- W2034773731 cites W2002328121 @default.
- W2034773731 cites W2011857906 @default.
- W2034773731 cites W2024813301 @default.
- W2034773731 cites W2038067219 @default.
- W2034773731 cites W2042375330 @default.
- W2034773731 cites W2052483024 @default.
- W2034773731 cites W2053502538 @default.
- W2034773731 cites W2059401704 @default.
- W2034773731 cites W2060532414 @default.
- W2034773731 cites W2072770001 @default.
- W2034773731 cites W2084270478 @default.
- W2034773731 cites W2091062905 @default.
- W2034773731 cites W2115481151 @default.
- W2034773731 cites W2158124545 @default.
- W2034773731 doi "https://doi.org/10.1021/ic971477n" @default.
- W2034773731 hasPublicationYear "1998" @default.
- W2034773731 type Work @default.
- W2034773731 sameAs 2034773731 @default.
- W2034773731 citedByCount "35" @default.
- W2034773731 countsByYear W20347737312012 @default.
- W2034773731 countsByYear W20347737312013 @default.
- W2034773731 countsByYear W20347737312014 @default.
- W2034773731 countsByYear W20347737312015 @default.
- W2034773731 countsByYear W20347737312016 @default.
- W2034773731 countsByYear W20347737312017 @default.
- W2034773731 countsByYear W20347737312019 @default.
- W2034773731 crossrefType "journal-article" @default.
- W2034773731 hasAuthorship W2034773731A5014383490 @default.
- W2034773731 hasAuthorship W2034773731A5047752377 @default.
- W2034773731 hasAuthorship W2034773731A5056552692 @default.
- W2034773731 hasAuthorship W2034773731A5086995669 @default.
- W2034773731 hasConcept C115624301 @default.
- W2034773731 hasConcept C155647269 @default.
- W2034773731 hasConcept C178790620 @default.
- W2034773731 hasConcept C185592680 @default.
- W2034773731 hasConcept C197404232 @default.
- W2034773731 hasConcept C2779463800 @default.
- W2034773731 hasConcept C2781311116 @default.
- W2034773731 hasConcept C42228675 @default.
- W2034773731 hasConcept C61276311 @default.
- W2034773731 hasConcept C71240020 @default.
- W2034773731 hasConcept C8010536 @default.
- W2034773731 hasConceptScore W2034773731C115624301 @default.
- W2034773731 hasConceptScore W2034773731C155647269 @default.
- W2034773731 hasConceptScore W2034773731C178790620 @default.
- W2034773731 hasConceptScore W2034773731C185592680 @default.
- W2034773731 hasConceptScore W2034773731C197404232 @default.
- W2034773731 hasConceptScore W2034773731C2779463800 @default.
- W2034773731 hasConceptScore W2034773731C2781311116 @default.
- W2034773731 hasConceptScore W2034773731C42228675 @default.
- W2034773731 hasConceptScore W2034773731C61276311 @default.
- W2034773731 hasConceptScore W2034773731C71240020 @default.
- W2034773731 hasConceptScore W2034773731C8010536 @default.
- W2034773731 hasIssue "7" @default.
- W2034773731 hasLocation W20347737311 @default.
- W2034773731 hasOpenAccess W2034773731 @default.
- W2034773731 hasPrimaryLocation W20347737311 @default.
- W2034773731 hasRelatedWork W1550031554 @default.
- W2034773731 hasRelatedWork W1998057223 @default.
- W2034773731 hasRelatedWork W2009826639 @default.
- W2034773731 hasRelatedWork W2070844528 @default.
- W2034773731 hasRelatedWork W2260173655 @default.
- W2034773731 hasRelatedWork W2283894052 @default.
- W2034773731 hasRelatedWork W2395756852 @default.
- W2034773731 hasRelatedWork W2949498525 @default.
- W2034773731 hasRelatedWork W2951503600 @default.
- W2034773731 hasRelatedWork W2952169498 @default.
- W2034773731 hasVolume "37" @default.
- W2034773731 isParatext "false" @default.
- W2034773731 isRetracted "false" @default.
- W2034773731 magId "2034773731" @default.
- W2034773731 workType "article" @default.