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- W2034774175 abstract "The size and flexibility of molecules in solutions has been studied by determining the intrinsic viscosities of diethylene glycol adipate oligomers (DEGA). The Huggins constant of the oligomer solutions in MEK has been found to be in the range 0.2–0.5 and to decrease with the functionality; it was independent of the mol.wt. in a series of similar functionalities. The intrinsic viscosity as a function of the mol.wt. is given by [η]=K0·M0.5, but is unreliable where the oligo-esters have differing functionalities. The found [η]-values have been used to estimate the average size of the molecules. The persistent length of the macromolecules depends on the number of OH-groups and increases on changing from the non-functional DEGA oligomers to the bifunctional. The found persistent length classifies the DEGA oligomers as flexible-chain polymers." @default.
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- W2034774175 date "1982-01-01" @default.
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- W2034774175 title "Intrinsic viscosities of diethylene glycol adipate solutions of various functionalities" @default.
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- W2034774175 doi "https://doi.org/10.1016/0032-3950(82)90217-9" @default.
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