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- W2034777030 abstract "New molecular rotors, [7.7](2,6)pyridinocyclophanes (monomers and dimers) embedding 1,3-dioxanes in the bridges, were investigated by variable-temperature NMR, molecular modeling, and single-crystal X-ray diffractometry. The nitrogen-inside rotation of the pyridine ring is more hindered in the derivatives with longer distance between the bridges (i.e., para > meta and 2,6-pyridylene > ortho) and can be chemically stopped by complexation with CF(3)SO(3)Ag. [structure: see text]" @default.
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- W2034777030 date "2006-05-19" @default.
- W2034777030 modified "2023-10-18" @default.
- W2034777030 title "Molecular Rotors: Design, Synthesis, Structural Analysis, and Silver Complex of New [7.7]Cyclophanes" @default.
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- W2034777030 doi "https://doi.org/10.1021/ol0610845" @default.
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