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• W2034778154 abstract "Polyaniline (PANI) films of superior homogeneity can be prepared by using functionalized protonic acids to protonate the polymer and simultaneously induce solubility, in the conducting form, in common organic solvents. The resistivity ϱ(T), of polyaniline (PANI) complexed with camphor sulfonic acid (CSA) exhibits a positive temperature coefficient for 180K 10, ϱ(T,H=0)exp(T−1/4). For samples with ϱ(1.2K)/ϱ(300K) ∼3–5, ϱ(T,H=0) T−β where β≈0.36, consistent with transport in the critical region near the metal-insulator (M-I) boundary, whereas ϱ(T,H=8Tesla) =ϱ0exp[(T0/T)1/4], indicating variable range hopping between localized states with mean localization length, Lc(H=8T)∼100–140A. Thus PANI-CSA is on the (M-I) boundary." @default.
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• W2034778154 date "1993-04-01" @default.
• W2034778154 modified "2023-09-22" @default.
• W2034778154 title "Metal-insulator transition in polyaniline doped with surfactant counter-ion" @default.
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• W2034778154 doi "https://doi.org/10.1016/0379-6779(93)90856-r" @default.
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