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- W2034778917 abstract "Platinum and ruthenium in carbon supported Pt and Pt–Ru catalysts were determined by direct and derivative spectrophotometric methods. Complexes of platinum and ruthenium with SnCl3− ligands (tin(II) chloride in HCl) were used to determine both metals in solutions obtained after digestion of the samples of the catalysts. Platinum in the Pt/C catalyst can be determined in solutions obtained by digestion of the samples in aqua regia. Derivative spectrophotometry was used to determine both metals in the presence of each other in solutions obtained after digestion of samples of the Pt–Ru/C catalyst in the mixture of HCl+HNO3 (6:1). The first derivative at 377 nm (`zero-crossing' point of ruthenium) and the second-derivative values at 495 nm (`zero-crossing' point of platinum) were used to estimate the concentration of platinum and ruthenium, respectively." @default.
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- W2034778917 date "1999-01-05" @default.
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- W2034778917 title "Determination of platinum and ruthenium in Pt and Pt–Ru catalysts with carbon support by direct and derivative spectrophotometry" @default.
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- W2034778917 doi "https://doi.org/10.1016/s0039-9140(98)00212-4" @default.
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