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• W2034779139 abstract "Femtosecond nonresonant multiphoton ionisation (fs-MPI) of the fragile biomolecule valyl-valine is compared with single photon ionisation (SPI) using time-of-flight mass spectrometry. Under conditions of comparable total ion yield the least amount of molecular ion dissociation is observed with 118 nm SPI (100 nJ cm−2) followed by 266 nm fs-MPI (25 mJ cm−2), then 400 nm, and 800 nm fs-MPI (230 mJ cm−2 and 1.3 J cm−2, respectively). The laser intensity dependence of the ion signal observed at 266 nm and 400 nm is consistent with a simple nonresonant MPI mechanism whereas at 800 nm the results suggest a transition from the MPI regime toward a field ionisation mechanism such as tunneling or barrier suppression ionisation." @default.
• W2034779139 created "2016-06-24" @default.
• W2034779139 creator A5067771918 @default.
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• W2034779139 date "2000-02-01" @default.
• W2034779139 modified "2023-10-14" @default.
• W2034779139 title "Single photon and femtosecond multiphoton ionisation of the dipeptide valyl-valine" @default.
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• W2034779139 doi "https://doi.org/10.1016/s1387-3806(99)00249-3" @default.
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