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- W2034782556 abstract "The site preference of boryl ligands in five-coordinate transition metal boryl complexes has been investigated with the aid of density functional theory calculations. The preferred site for a boryl ligand depends on the electron count of the complex under consideration. Our studies show that the very strong σ-donating boryl ligands choose to occupy coordination sites such that those orbitals accommodating metal d electrons have minimal metal−boryl σ*-antibonding character." @default.
- W2034782556 created "2016-06-24" @default.
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- W2034782556 date "2004-03-18" @default.
- W2034782556 modified "2023-10-03" @default.
- W2034782556 title "Structural Analysis of Five-Coordinate Transition Metal Boryl Complexes with Different d-Electron Configurations" @default.
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- W2034782556 doi "https://doi.org/10.1021/ic035248e" @default.
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