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- W2034782829 abstract "Previous studies of methane chemisorbing on metals have all been interpreted in terms of tunneling, but the evidence is inconclusive. Chemisorption rates on a W(211) surface at room temperature have therefore been measured for CH4 and CD4 from a molecular beam at Tg > 550 K. Only small differences are found in the activation energies. Models for tunneling from translationally hot molecules, as well as from excited vibrational states, are explored as possible descriptions of chemisorption and found incompatible with small isotope effects observed." @default.
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- W2034782829 date "1987-01-01" @default.
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- W2034782829 title "Activated chemisorption of methane and tunneling" @default.
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- W2034782829 doi "https://doi.org/10.1016/0039-6028(87)90108-7" @default.
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