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- W2034783321 abstract "Λ- and Δ-enantiomers of cis-[CoBr(NH3)(en)2]Br2 were obtained by absolute asymmetric synthesis. The interactions between the achiral 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) and two chiral cationic Co(III) complexes were studied by UV-vis spectroscopy, circular dichroism (CD), fluorescence spectroscopy and atomic force microscopy (AFM). It was found that the cationic Co(III) complexes can induce the formation of chiral porphyrin J-aggregates, that the metal-centered chirality can be transferred to the J-aggregates, and that the chirality was able to be memorized and amplified in the porphyrin J-aggregates. Therefore, this should be a good chiral model for understanding similar processes in physical and biological systems." @default.
- W2034783321 created "2016-06-24" @default.
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- W2034783321 date "2010-01-01" @default.
- W2034783321 modified "2023-10-17" @default.
- W2034783321 title "Transformation, memorization and amplification of chirality in cationic Co(iii) complex–porphyrin aggregates" @default.
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- W2034783321 doi "https://doi.org/10.1039/c0nj00022a" @default.
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