Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034785464> ?p ?o ?g. }
- W2034785464 endingPage "11333" @default.
- W2034785464 startingPage "11324" @default.
- W2034785464 abstract "The isoleptic organonickel complexes [(bpy)Ni(Mes)X] (bpy ) 2,2'-bipyridine; Mes ) 2,4,6-trimethylphenyl; X ) F,Cl, Br, or I, and for comparison X ) OMe and SCN) have been investigated by multiple spectroscopic means.Their structures have been determined in part by single-crystal X-ray diffraction, the full series by extended X-ray absorption fine structure. The long-wavelength charge transfer absorptions (mainly metal-to-ligand charge transfer)obtain contributions from the mesityl coligand but are almost invariable upon variation of X. UV-vis spectroscopy allowed investigation of the solvolysis reaction [(bpy)Ni(Mes)X] + Solv a [(bpy)Ni(Mes)(Solv)]+ + X-, which occurs very fast for X ) I (k ) 0.176(4) M(-1) s(-1)) or Br but very slow for X ) Cl (k ) 5.18(5) x 10(-5) M(-1) cm(-1))or F. Quantum chemical (density functional theory) calculations on the geometry, electronic states, and electronic transitions (time-dependent density functional theory) are very helpful for detailed insight into the role the X coligands play in these complexes. The combination of methods reveals rather strong, highly covalent Ni-X bonds for all halide coligands but marginal pi-donation." @default.
- W2034785464 created "2016-06-24" @default.
- W2034785464 creator A5025123870 @default.
- W2034785464 creator A5031474784 @default.
- W2034785464 creator A5035374856 @default.
- W2034785464 creator A5046763720 @default.
- W2034785464 creator A5056860796 @default.
- W2034785464 creator A5059647078 @default.
- W2034785464 creator A5068458229 @default.
- W2034785464 date "2008-10-29" @default.
- W2034785464 modified "2023-10-18" @default.
- W2034785464 title "Halide Ligands—More Than Just σ-Donors? A Structural and Spectroscopic Study of Homologous Organonickel Complexes" @default.
- W2034785464 cites W1964270001 @default.
- W2034785464 cites W1966162293 @default.
- W2034785464 cites W1966215023 @default.
- W2034785464 cites W1966686144 @default.
- W2034785464 cites W1975878087 @default.
- W2034785464 cites W1976858794 @default.
- W2034785464 cites W1977942663 @default.
- W2034785464 cites W1981368803 @default.
- W2034785464 cites W1986257730 @default.
- W2034785464 cites W1995375367 @default.
- W2034785464 cites W2001018153 @default.
- W2034785464 cites W2001691987 @default.
- W2034785464 cites W2002788226 @default.
- W2034785464 cites W2003575469 @default.
- W2034785464 cites W2004055530 @default.
- W2034785464 cites W2008254582 @default.
- W2034785464 cites W2011421995 @default.
- W2034785464 cites W2013464543 @default.
- W2034785464 cites W2027671486 @default.
- W2034785464 cites W2028475408 @default.
- W2034785464 cites W2029041674 @default.
- W2034785464 cites W2029071568 @default.
- W2034785464 cites W2029217624 @default.
- W2034785464 cites W2030273754 @default.
- W2034785464 cites W2036334910 @default.
- W2034785464 cites W2039559098 @default.
- W2034785464 cites W2044580907 @default.
- W2034785464 cites W2050028596 @default.
- W2034785464 cites W2051600817 @default.
- W2034785464 cites W2051848643 @default.
- W2034785464 cites W2053437375 @default.
- W2034785464 cites W2062990771 @default.
- W2034785464 cites W2065878613 @default.
- W2034785464 cites W2067011309 @default.
- W2034785464 cites W2071129190 @default.
- W2034785464 cites W2078177715 @default.
- W2034785464 cites W2082925983 @default.
- W2034785464 cites W2086957099 @default.
- W2034785464 cites W2088991848 @default.
- W2034785464 cites W2094642658 @default.
- W2034785464 cites W2109189427 @default.
- W2034785464 cites W2109460649 @default.
- W2034785464 cites W2140159113 @default.
- W2034785464 cites W2143981217 @default.
- W2034785464 cites W2144692300 @default.
- W2034785464 cites W2150114636 @default.
- W2034785464 cites W2150345533 @default.
- W2034785464 cites W2150638051 @default.
- W2034785464 cites W2166821952 @default.
- W2034785464 cites W2483930702 @default.
- W2034785464 cites W28256087 @default.
- W2034785464 cites W2949214706 @default.
- W2034785464 cites W2950907955 @default.
- W2034785464 cites W2951119746 @default.
- W2034785464 cites W2951861708 @default.
- W2034785464 cites W2953179816 @default.
- W2034785464 cites W2953369495 @default.
- W2034785464 cites W4251868966 @default.
- W2034785464 cites W4252645107 @default.
- W2034785464 doi "https://doi.org/10.1021/ic8007365" @default.
- W2034785464 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18959362" @default.
- W2034785464 hasPublicationYear "2008" @default.
- W2034785464 type Work @default.
- W2034785464 sameAs 2034785464 @default.
- W2034785464 citedByCount "43" @default.
- W2034785464 countsByYear W20347854642012 @default.
- W2034785464 countsByYear W20347854642014 @default.
- W2034785464 countsByYear W20347854642015 @default.
- W2034785464 countsByYear W20347854642016 @default.
- W2034785464 countsByYear W20347854642017 @default.
- W2034785464 countsByYear W20347854642018 @default.
- W2034785464 countsByYear W20347854642019 @default.
- W2034785464 countsByYear W20347854642020 @default.
- W2034785464 countsByYear W20347854642021 @default.
- W2034785464 countsByYear W20347854642022 @default.
- W2034785464 countsByYear W20347854642023 @default.
- W2034785464 crossrefType "journal-article" @default.
- W2034785464 hasAuthorship W2034785464A5025123870 @default.
- W2034785464 hasAuthorship W2034785464A5031474784 @default.
- W2034785464 hasAuthorship W2034785464A5035374856 @default.
- W2034785464 hasAuthorship W2034785464A5046763720 @default.
- W2034785464 hasAuthorship W2034785464A5056860796 @default.
- W2034785464 hasAuthorship W2034785464A5059647078 @default.
- W2034785464 hasAuthorship W2034785464A5068458229 @default.
- W2034785464 hasConcept C115624301 @default.
- W2034785464 hasConcept C116569031 @default.