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- W2034786874 abstract "Construction of the polytetrahydrofuranyl building blocks 6−10 from the common bissiloxyacetone precursor 11 is detailed. The approach is concise and, for the bis-(THF) pair, capitalizes on the full retention of configuration observed during the rhodium-promoted decarbonylation of aldehydes 18 and 19. The capability of the title compounds to associate with alkali metal ions in solution and the gas phase has demonstrated a preference for Li+ over Na+ and K+ in all cases, with 6 and 7 exhibiting somewhat higher binding selectivities than 8−10. The relative energy orderings of attainable conformations with the bis-THF and tris-THF series were explored computationally. The various envelope arrangements present in the individual THF units are shown to play a significant role alongside prevailing gauche interactions. The “gauche effect” is shown computationally not to be an accurate predictor of the lowest energy conformer." @default.
- W2034786874 created "2016-06-24" @default.
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- W2034786874 date "2007-07-13" @default.
- W2034786874 modified "2023-10-18" @default.
- W2034786874 title "Synthesis of, and Structural Assignments to the Stereoisomers of Bis (2,2‘)- and Tris (2,2‘,2‘ ‘)-Tetrahydrofurans: Conformational Features and Ionic Binding Capacities of These Gateway Polycyclic Networks" @default.
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- W2034786874 doi "https://doi.org/10.1021/jo0708238" @default.
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