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- W2034790265 abstract "SiO2@Gd2MoO6:Eu3+ core–shell phosphors were prepared by the sol–gel process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDS), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as kinetic decays were used to characterize the resulting SiO2@Gd2MoO6:Eu3+ core–shell phosphors. The XRD results demonstrate that the Gd2MoO6:Eu3+ layers on the SiO2 spheres begin to crystallize after annealing at 600 °C and the crystallinity increases with raising the annealing temperature. The obtained core–shell phosphors have a near perfect spherical shape with narrow size distribution (average size ca. 600 nm), are not agglomerated, and have a smooth surface. The thickness of the Gd2MoO6:Eu3+ shells on the SiO2 cores could be easily tailored by varying the number of deposition cycles (50 nm for four deposition cycles). The Eu3+ shows a strong PL luminescence (dominated by 5D0–7F2 red emission at 613 nm) under the excitation of 307 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the number of coating cycles." @default.
- W2034790265 created "2016-06-24" @default.
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- W2034790265 date "2006-08-01" @default.
- W2034790265 modified "2023-10-14" @default.
- W2034790265 title "Sol–gel growth of Gd2MoO6:Eu3+ nanocrystalline layers on SiO2 spheres (SiO2@Gd2MoO6:Eu3+) and their luminescent properties" @default.
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- W2034790265 doi "https://doi.org/10.1016/j.susc.2006.06.018" @default.
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