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- W2034791729 abstract "The synthesis of novel diblock copolymers consisting of a semifluorinated block of poly(1H,1H,2H,2H-perfluorooctyl methacrylate) (PFOMA) and a hydrocarbon block of polycaprolactone (PFOMA-b-PCL) was achieved by the combination of enzymatic ring-opening polymerization (eROP) and atom transfer radical polymerization (ATRP). The chemoenzymatic synthesis of diblock copolymers from a bifunctional initiator in two consecutive steps was investigated. A polycaprolactone (PCL) macroinitiator was obtained via enzymatic ring-opening polymerization initiated by the bifunctional initiator. A PFOMA block was then grown from this PCL macroinitiator. In addition, block copolymers were successfully prepared by a two-step−one-pot synthesis using a sequential monomer addition technique." @default.
- W2034791729 created "2016-06-24" @default.
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- W2034791729 date "2005-12-22" @default.
- W2034791729 modified "2023-10-16" @default.
- W2034791729 title "Synthesis of Semifluorinated Block Copolymers Containing Poly(ε-caprolactone) by the Combination of ATRP and Enzymatic ROP in scCO<sub>2</sub>" @default.
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- W2034791729 doi "https://doi.org/10.1021/ma052142p" @default.
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