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- W2034794136 abstract "A beam of ${mathrm{O}}_{2}^{ensuremath{-}}$ ions, extracted from a glow discharge in ${mathrm{N}}_{2}$O, is crossed with the linearly polarized intracavity photon beam of an argon-ion laser (4880 AA{}). Electrons photodetached at right angles to the crossed beams are energy filtered by a hemispherical analyzer. The electron energy spectra are characteristic of photodetachment from the ${v}^{ensuremath{'}}=0$ state of ${mathrm{O}}_{2}^{ensuremath{-}}$ to the $X^{3}ensuremath{Sigma}_{g}^{ensuremath{-}}$ and $a^{1}ensuremath{Delta}_{g}$ states of ${mathrm{O}}_{2}$. Vibrational state analysis is facilitated by the use of isotopes. The electron affinity obtained is 0.440 ifmmodepmelsetextpmfi{} 0.008 eV. Additionally, we have measured the relative transition probabilities as a function of final vibrational state and the angular distributions of the outgoing electrons. The relative intensities, corrected by the angular distributions, determine through Franck-Condon-factor analysis the internuclear distance for the negative ion. We find ${mathcal{r}}_{e}^{ensuremath{'}ensuremath{'}}=1.341ifmmodepmelsetextpmfi{}0.010$ AA{} and therefore ${B}_{e}^{ensuremath{'}ensuremath{'}}=1.17ifmmodepmelsetextpmfi{}0.02$ ${mathrm{cm}}^{ensuremath{-}1}$." @default.
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- W2034794136 date "1972-08-01" @default.
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- W2034794136 title "Molecular Photodetachment Spectrometry. II. The Electron Affinity of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and the Structure of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msubsup><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn…" @default.
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- W2034794136 doi "https://doi.org/10.1103/physreva.6.631" @default.
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