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- W2034795787 abstract "Equimolar quantities of [MI2(CO)3(NCMe)2] (M = Mo or W) and triphos {triphos = Ph2P(CH2)2PPh(CH2)2PPh2} react in CH2Cl2 at room temperature to give the dicarbonyl molybdenum complex [MoI2(CO)2(η3-triphos)] (1) or the tricarbonyl tungsten complex [WI2(CO)3(η2-triphos)] (2). Refluxing (2) in CH2Cl2 for 15 min gave the η3-triphos complex [WI2(CO)2(η3-triphos)] (3). Preliminary studies of the reaction chemistry of (2) as a monodentate phosphine ligand are also described." @default.
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- W2034795787 date "1994-01-01" @default.
- W2034795787 modified "2023-10-18" @default.
- W2034795787 title "Seven-coordinate triphos {triphos = Ph2P(CH2)2PPh2} complexes of molybdenum(II) and tungsten(II): [WI2(CO)3(η2-triphos)], a novel monodentate phosphine ligand" @default.
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- W2034795787 doi "https://doi.org/10.1016/s0277-5387(00)81670-8" @default.
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