Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034800475> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2034800475 endingPage "2033" @default.
- W2034800475 startingPage "2020" @default.
- W2034800475 abstract "The current article describes the TG and DT analyses of divalent Zn, Cd, and Hg dithiocarbamato (dtc) complexes and their adducts (dchdtc = N,N-dicyclohexyldithiocarbamate anion, 4-mpzdtc = 4-methylpiperazinecarbodithioato anion, padtc = N,N′-(iminodiethylene)bisphthalimidedithiocarbamate anion, pipdtc = piperidinecarbodithioate anion, 1,10-phen = 1,10-phenanthroline, and 2,2′-bipy = 2,2′-bipyridine) along with the structural reinvestigation of [Hg(tetds)I 2 ], where tetds = tetraethylthiuramdisulfide. In the case of Zn(II) and Cd(II) dithiocarbamates and their nitrogenous adducts, thermal decomposition of the nitrogenous bases is followed by the decay of dithiocarbamate leading to the formation of ZnS or CdS as residue. The interaction of iodine with [Hg(dedtc) 2 ] in CHCl 3 results in the oxidation of diethyldithiocarbamate leading to the formation of [Hg(tetds)I 2 ], and the structure was redetermined because the earlier determination was by a Polaroid crystallographic technique with a higher R value. The S-Hg-I bond angles [105.09(3); 105.59(3); 109.26(3), and 100.99(3)°] indicate the near tetrahedral environment around the metal ion. 1 H and 13 C NMR spectra of the complex were analyzed. Whether the product formed upon oxidation is a disulfide or an iodo-substituted product, in the present investigation, is clearly decided by the bulkiness of the substituent attached to the nitrogen. Interestingly, the steric influence is a deciding factor only in the case of mercury compounds and the dithiocarbamates involving Zn, Cd forms of the disulfide complexes." @default.
- W2034800475 created "2016-06-24" @default.
- W2034800475 creator A5043623254 @default.
- W2034800475 creator A5053367276 @default.
- W2034800475 creator A5054196470 @default.
- W2034800475 creator A5085522770 @default.
- W2034800475 date "2009-07-22" @default.
- W2034800475 modified "2023-09-30" @default.
- W2034800475 title "Spectral, BVS, and Thermal Studies on Bisdithiocarbamates of Divalent Zn, Cd, and Their Adducts: Single Crystal X-Ray Structure Redetermination of (Diiodo) (Tetraethylthiuramdisulfide)mercury(II), [Hg(tetds)I<sub>2</sub>]" @default.
- W2034800475 cites W1976075691 @default.
- W2034800475 cites W1977622579 @default.
- W2034800475 cites W1986493940 @default.
- W2034800475 cites W1996047389 @default.
- W2034800475 cites W2005219931 @default.
- W2034800475 cites W2012181296 @default.
- W2034800475 cites W2018766848 @default.
- W2034800475 cites W2045597708 @default.
- W2034800475 cites W2050797811 @default.
- W2034800475 cites W2063705072 @default.
- W2034800475 cites W2071883351 @default.
- W2034800475 cites W2074019256 @default.
- W2034800475 cites W2079180178 @default.
- W2034800475 cites W2083419439 @default.
- W2034800475 cites W2092841803 @default.
- W2034800475 cites W2101741054 @default.
- W2034800475 cites W2148066840 @default.
- W2034800475 cites W2165334127 @default.
- W2034800475 cites W2338341614 @default.
- W2034800475 cites W262962863 @default.
- W2034800475 cites W2908534095 @default.
- W2034800475 doi "https://doi.org/10.1080/10426500802418016" @default.
- W2034800475 hasPublicationYear "2009" @default.
- W2034800475 type Work @default.
- W2034800475 sameAs 2034800475 @default.
- W2034800475 citedByCount "21" @default.
- W2034800475 countsByYear W20348004752012 @default.
- W2034800475 countsByYear W20348004752013 @default.
- W2034800475 countsByYear W20348004752014 @default.
- W2034800475 countsByYear W20348004752015 @default.
- W2034800475 countsByYear W20348004752016 @default.
- W2034800475 countsByYear W20348004752017 @default.
- W2034800475 countsByYear W20348004752021 @default.
- W2034800475 countsByYear W20348004752023 @default.
- W2034800475 crossrefType "journal-article" @default.
- W2034800475 hasAuthorship W2034800475A5043623254 @default.
- W2034800475 hasAuthorship W2034800475A5053367276 @default.
- W2034800475 hasAuthorship W2034800475A5054196470 @default.
- W2034800475 hasAuthorship W2034800475A5085522770 @default.
- W2034800475 hasConcept C108204754 @default.
- W2034800475 hasConcept C115624301 @default.
- W2034800475 hasConcept C155647269 @default.
- W2034800475 hasConcept C160434732 @default.
- W2034800475 hasConcept C178790620 @default.
- W2034800475 hasConcept C179104552 @default.
- W2034800475 hasConcept C185592680 @default.
- W2034800475 hasConcept C199360897 @default.
- W2034800475 hasConcept C201194858 @default.
- W2034800475 hasConcept C2777545050 @default.
- W2034800475 hasConcept C2777777548 @default.
- W2034800475 hasConcept C2778689049 @default.
- W2034800475 hasConcept C41008148 @default.
- W2034800475 hasConcept C71240020 @default.
- W2034800475 hasConcept C8010536 @default.
- W2034800475 hasConceptScore W2034800475C108204754 @default.
- W2034800475 hasConceptScore W2034800475C115624301 @default.
- W2034800475 hasConceptScore W2034800475C155647269 @default.
- W2034800475 hasConceptScore W2034800475C160434732 @default.
- W2034800475 hasConceptScore W2034800475C178790620 @default.
- W2034800475 hasConceptScore W2034800475C179104552 @default.
- W2034800475 hasConceptScore W2034800475C185592680 @default.
- W2034800475 hasConceptScore W2034800475C199360897 @default.
- W2034800475 hasConceptScore W2034800475C201194858 @default.
- W2034800475 hasConceptScore W2034800475C2777545050 @default.
- W2034800475 hasConceptScore W2034800475C2777777548 @default.
- W2034800475 hasConceptScore W2034800475C2778689049 @default.
- W2034800475 hasConceptScore W2034800475C41008148 @default.
- W2034800475 hasConceptScore W2034800475C71240020 @default.
- W2034800475 hasConceptScore W2034800475C8010536 @default.
- W2034800475 hasIssue "8" @default.
- W2034800475 hasLocation W20348004751 @default.
- W2034800475 hasOpenAccess W2034800475 @default.
- W2034800475 hasPrimaryLocation W20348004751 @default.
- W2034800475 hasRelatedWork W2035298607 @default.
- W2034800475 hasRelatedWork W2049614080 @default.
- W2034800475 hasRelatedWork W2084864691 @default.
- W2034800475 hasRelatedWork W2094595706 @default.
- W2034800475 hasRelatedWork W222767794 @default.
- W2034800475 hasRelatedWork W2378479697 @default.
- W2034800475 hasRelatedWork W2386037739 @default.
- W2034800475 hasRelatedWork W2488490601 @default.
- W2034800475 hasRelatedWork W2500440176 @default.
- W2034800475 hasRelatedWork W3143661298 @default.
- W2034800475 hasVolume "184" @default.
- W2034800475 isParatext "false" @default.
- W2034800475 isRetracted "false" @default.
- W2034800475 magId "2034800475" @default.
- W2034800475 workType "article" @default.