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• W2034800657 abstract "For the last decade ionic liquids have been regarded as compounds of interest by the academic and industrial communities. These compounds present several advantages when compared to other typical solvents. However, because of their novelty, a deep understanding of their phase behaviour and their interactions with other components is still needed. In this work, we made a review of literature studies on modelling systems with ionic liquids using equation of state models. Furthermore, we applied the Cubic Plus Association (CPA) equation of state to describe the phase behaviour of two ionic liquids, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C4mim][NTf2]). The first step was to study an adequate approach for the determination of pure component parameters for the ionic liquids. The parameters were obtained by fitting the predictions of the model to experimental vapour pressure and liquid density data. The parameters provide a good description of both experimental vapour pressures and liquid density, with maximum percentage deviations of respectively 8.9 and 1.3% for [C2mim][NTf2] and 5.7 and 0.5% for [C4mim][NTf2]. Different sets of pure component parameters for each ionic liquid were considered and their suitability to describe the behaviour of ionic liquids was evaluated by modelling the vapour–liquid equilibria (VLE) of mixtures with CO2 and the liquid–liquid equilibria (LLE) with water. The results for VLE proved to be very good in the range of pressures studied when using one temperature-independent binary interaction parameter, with percentage deviations in pressure between 8 and 13% for [C2mim][NTf2] and around 12% for [C4mim][NTf2]. For the LLE of ionic liquids with water a temperature-independent binary interaction parameter was also used, but the results do not describe the experimental data as well as with the VLE, with percentage deviations ranging from 4 to 100%. However, for some of the sets of pure component parameters a good description of the experimental data is obtained and work is in progress for improving the modelling of LLE with the CPA equation of state." @default.
• W2034800657 created "2016-06-24" @default.
• W2034800657 creator A5016182727 @default.
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• W2034800657 creator A5058028247 @default.
• W2034800657 creator A5060430333 @default.
• W2034800657 creator A5070686398 @default.
• W2034800657 date "2012-10-01" @default.
• W2034800657 modified "2023-10-16" @default.
• W2034800657 title "Equation of state modelling of systems with ionic liquids: Literature review and application with the Cubic Plus Association (CPA) model" @default.
• W2034800657 cites W153242017 @default.
• W2034800657 cites W1919048594 @default.
• W2034800657 cites W1963550508 @default.
• W2034800657 cites W1965350133 @default.
• W2034800657 cites W1966582357 @default.
• W2034800657 cites W1966842983 @default.
• W2034800657 cites W1969883977 @default.
• W2034800657 cites W1971518711 @default.
• W2034800657 cites W1974430435 @default.
• W2034800657 cites W1975337340 @default.
• W2034800657 cites W1977803061 @default.
• W2034800657 cites W1978962015 @default.
• W2034800657 cites W1979014625 @default.
• W2034800657 cites W1980961637 @default.
• W2034800657 cites W1982070023 @default.
• W2034800657 cites W1982479518 @default.
• W2034800657 cites W1983185582 @default.
• W2034800657 cites W1983658470 @default.
• W2034800657 cites W1984895412 @default.
• W2034800657 cites W1985087154 @default.
• W2034800657 cites W1986994418 @default.
• W2034800657 cites W1987761437 @default.
• W2034800657 cites W1989422919 @default.
• W2034800657 cites W1989777237 @default.
• W2034800657 cites W1990627763 @default.
• W2034800657 cites W1992691508 @default.
• W2034800657 cites W1992803850 @default.
• W2034800657 cites W1994349999 @default.
• W2034800657 cites W1998022382 @default.
• W2034800657 cites W1998926043 @default.
• W2034800657 cites W1999825056 @default.
• W2034800657 cites W2000125548 @default.
• W2034800657 cites W2001019903 @default.
• W2034800657 cites W2008001354 @default.
• W2034800657 cites W2008312376 @default.
• W2034800657 cites W2008478588 @default.
• W2034800657 cites W2009313517 @default.
• W2034800657 cites W2009619152 @default.
• W2034800657 cites W2012024491 @default.
• W2034800657 cites W2013229454 @default.
• W2034800657 cites W2013748968 @default.
• W2034800657 cites W2014464559 @default.
• W2034800657 cites W2015540321 @default.
• W2034800657 cites W2016172486 @default.
• W2034800657 cites W2016722203 @default.
• W2034800657 cites W2016917378 @default.
• W2034800657 cites W2017905717 @default.
• W2034800657 cites W2018534053 @default.
• W2034800657 cites W2018813307 @default.
• W2034800657 cites W2019408115 @default.
• W2034800657 cites W2020959202 @default.
• W2034800657 cites W2021908094 @default.
• W2034800657 cites W2023152482 @default.
• W2034800657 cites W2024795243 @default.
• W2034800657 cites W2026210300 @default.
• W2034800657 cites W2026546960 @default.
• W2034800657 cites W2027022245 @default.
• W2034800657 cites W2032114096 @default.
• W2034800657 cites W2033502913 @default.
• W2034800657 cites W2034610557 @default.
• W2034800657 cites W2035417713 @default.
• W2034800657 cites W2035698876 @default.
• W2034800657 cites W2036083618 @default.
• W2034800657 cites W2037652210 @default.
• W2034800657 cites W2037794393 @default.
• W2034800657 cites W2037809631 @default.
• W2034800657 cites W2039769754 @default.
• W2034800657 cites W2041662371 @default.
• W2034800657 cites W2042190976 @default.
• W2034800657 cites W2044410057 @default.
• W2034800657 cites W2044585912 @default.
• W2034800657 cites W2048164835 @default.
• W2034800657 cites W2050147949 @default.
• W2034800657 cites W2051493204 @default.
• W2034800657 cites W2052536448 @default.
• W2034800657 cites W2052981708 @default.
• W2034800657 cites W2053636610 @default.
• W2034800657 cites W2055942354 @default.
• W2034800657 cites W2056139823 @default.
• W2034800657 cites W2056324761 @default.
• W2034800657 cites W2058342289 @default.
• W2034800657 cites W2059421684 @default.
• W2034800657 cites W2061011942 @default.
• W2034800657 cites W2062210002 @default.
• W2034800657 cites W2063840090 @default.
• W2034800657 cites W2064637031 @default.
• W2034800657 cites W2064796203 @default.
• W2034800657 cites W2065756809 @default.

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