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- W203480967 abstract "The Ru/ZnO (0.5% Ru) system, prepared by decomposition of Ru 3 (CO) 12 on ZnO, was studied. The IR spectrum of CO adsorbed on H 2 reduced samples gives evidence of Ru x+ (CO) n (x,n=2,3) surface complexes. After heating at 423–523 K the CO further reduces the Ru x+ (CO) n complexes. The spectrum of CO adsorbed after this treatment can be interpreted in term of linear Ru°-CO (γ=2000 cm −1 ) on very small clusters and Ru-CO bridged anionic surface species (v = 1900–1820 cm −1 ). The formation of the last species, unusual on Ru, is favored in this case by an electron transfer from the reduced n-ZnO semiconductor to the small Ru particles." @default.
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- W203480967 date "1989-01-01" @default.
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- W203480967 title "An Infrared Study of Co Adsorbed on a Ru/Zno Catalyst" @default.
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- W203480967 doi "https://doi.org/10.1016/s0167-2991(08)60706-5" @default.
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