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- W2034828020 abstract "The reactions of [ReOX 3 (EPh 3 ) 2 ] with 8-hydroxyquinoline-2-carboxylic acid (Hhquin-2-COOH) have been examined and [ReOX 2 (hquin-2-COOH)(EPh 3 )] · MeCN (X = Cl, Br; E = As, P) complexes have been obtained. All the complexes were characterised by IR, UV–Vis spectroscopy and elemental analysis. The crystal and molecular structures have been determined for [ReOCl 2 (hquin-2-COOH)(AsPh 3 )] · MeCN and [ReOCl 2 (hquin-2-COOH)(PPh 3 )] · MeCN. The electronic structure of [ReOCl 2 (hquin-2-COOH)(AsPh 3 )] has been calculated with the density functional theory (DFT) method, and TDDFT calculations have been employed to produce a hundred of singlet excited-states starting from the ground-state geometry optimized in the gas phase." @default.
- W2034828020 created "2016-06-24" @default.
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- W2034828020 date "2008-01-01" @default.
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- W2034828020 title "Reactivity of oxorhenium(V) complexes towards 8-hydroxyquinoline-2-carboxylic acid: X-ray structure of [ReOCl2(hquin-2-COOH)(AsPh3)]·MeCN and [ReOCl2(hquin-2-COOH)(PPh3)]·MeCN complexes. DFT and TDDFT calculations for [ReOCl2(hquin-2-COOH)(AsPh3)]" @default.
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- W2034828020 doi "https://doi.org/10.1016/j.poly.2007.09.019" @default.
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