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- W2034831681 abstract "The equilibrium constants for hydrogen–deuterium self-exchange in hydrogen sulfide and hydrogen selenide have been studied over a wide range of deuterium atom percent using a pulsed-molecular-beam quadrupole mass filter. KHDS was found to be 3.88 ± 0.03 at 24.0 ± 0.4°C and KHDSe was found to be 3.92 ± 0.04 at 22 ± 1°C. The experimental results agree with calculations from spectroscopic data to within 1%. It is shown that equilibrium constants for self-exchange reactions in systems where two hydrogenic species are exchanged tend toward the geometric mean value of K = 4 in the series H2O:H2S:H2Se as expected from theory." @default.
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- W2034831681 date "1970-02-15" @default.
- W2034831681 modified "2023-10-17" @default.
- W2034831681 title "Hydrogen–Deuterium Self‐Exchange in Hydrogen Sulfide and Hydrogen Selenide as Studied with a Pulsed‐Molecular‐Beam Quadrupole Mass Filter" @default.
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- W2034831681 doi "https://doi.org/10.1063/1.1673243" @default.
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