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- W2034831810 abstract "Abstract The photopolymerization of methyl methacrylate with benzyl triphenylphosphonium bromide has been studied in order to assess whether this system follows a living radical polymerization mechanism. Rate of polymerization is found to increase linearly with monomer concentration and 0.31 power with respect to photoinitiator concentration. The overall activation energy is 27.7 kJ/mol within the studied temperature range 25–40°. Hydroquinone inhibits the polymerization. The molecular weight of the resulting polymer does not increase with increase with conversion and time. This result indicates that the system does not conform to the living radical polymerization model and is a case of ordinary radical polymerization." @default.
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- W2034831810 date "1993-04-01" @default.
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- W2034831810 title "Radical polymerization of methyl methacrylate with benzyl triphenylphosphonium bromide" @default.
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