FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034831987> ?p ?o ?g. }

• W2034831987 endingPage "1387" @default.
• W2034831987 startingPage "1379" @default.
• W2034831987 abstract "The reaction of ferric chloride and β-diketones (HL) in alkaline methanol solution represents a good synthetic route to hexairon(III) clusters [MFe6-(OCH3)12(L)6]+ (M = Na, Li), which exhibit an unusual sixfold molecular symmetry. Single-crystal X-ray diffraction showed that the six octahedrally coordinated iron(III) ions define a ring and are linked by twelve bridging methoxide ligands. The resulting [Fe6(OCH3)12] skeleton has the remarkable property of acting as a host for an alkali-metal ion both in the solid state and in organic solution, as demonstrated by 23Na and 7Li NMR experiments. The magnetic behavior of these systems is consistent with the presence of a nonmagnetic S = 0 ground state and of antiferromagnetic exchange interactions between the high-spin ferric ions. The energy of the excited states was studied in detail by high-field DC and pulsed-field differential magnetization experiments at 0.7 and 1.5 K. Single-crystal susceptibility measurements at variable temperature revealed a sizeable magnetic anisotropy, which has been successfully analyzed in terms of single-ion and dipolar contributions. The results are relevant to research into the origin of superparamagnetic-type behavior in transition-metal clusters." @default.
• W2034831987 created "2016-06-24" @default.
• W2034831987 creator A5000680390 @default.
• W2034831987 creator A5021530387 @default.
• W2034831987 creator A5026681457 @default.
• W2034831987 creator A5056152624 @default.
• W2034831987 creator A5068229812 @default.
• W2034831987 creator A5071471585 @default.
• W2034831987 creator A5077738215 @default.
• W2034831987 date "1996-11-01" @default.
• W2034831987 modified "2023-10-17" @default.
• W2034831987 title "Synthesis, Crystal Structure, Magnetism, and Magnetic Anisotropy of Cyclic Clusters Comprising six Iron(III) Ions and Entrapping Alkaline Ions" @default.
• W2034831987 cites W1616679551 @default.
• W2034831987 cites W1967852636 @default.
• W2034831987 cites W1974972418 @default.
• W2034831987 cites W1979220915 @default.
• W2034831987 cites W1980040283 @default.
• W2034831987 cites W1983826701 @default.
• W2034831987 cites W1991994013 @default.
• W2034831987 cites W2000223983 @default.
• W2034831987 cites W2000619473 @default.
• W2034831987 cites W2016965625 @default.
• W2034831987 cites W2017215042 @default.
• W2034831987 cites W2017628294 @default.
• W2034831987 cites W2028797835 @default.
• W2034831987 cites W2033493424 @default.
• W2034831987 cites W2035251747 @default.
• W2034831987 cites W2040846332 @default.
• W2034831987 cites W2041553729 @default.
• W2034831987 cites W2044958633 @default.
• W2034831987 cites W2051359785 @default.
• W2034831987 cites W2054508750 @default.
• W2034831987 cites W2061477298 @default.
• W2034831987 cites W2068034648 @default.
• W2034831987 cites W2070387267 @default.
• W2034831987 cites W2074558603 @default.
• W2034831987 cites W2082833800 @default.
• W2034831987 cites W2089586101 @default.
• W2034831987 cites W2089740902 @default.
• W2034831987 cites W2089996198 @default.
• W2034831987 cites W2095057286 @default.
• W2034831987 cites W2115697270 @default.
• W2034831987 cites W2117484137 @default.
• W2034831987 cites W2126849335 @default.
• W2034831987 cites W2160849974 @default.
• W2034831987 cites W2227313626 @default.
• W2034831987 cites W2477462889 @default.
• W2034831987 cites W2949525897 @default.
• W2034831987 cites W2951238698 @default.
• W2034831987 doi "https://doi.org/10.1002/chem.19960021109" @default.
• W2034831987 hasPublicationYear "1996" @default.
• W2034831987 type Work @default.
• W2034831987 sameAs 2034831987 @default.
• W2034831987 citedByCount "137" @default.
• W2034831987 countsByYear W20348319872012 @default.
• W2034831987 countsByYear W20348319872013 @default.
• W2034831987 countsByYear W20348319872015 @default.
• W2034831987 countsByYear W20348319872016 @default.
• W2034831987 countsByYear W20348319872017 @default.
• W2034831987 countsByYear W20348319872018 @default.
• W2034831987 countsByYear W20348319872019 @default.
• W2034831987 countsByYear W20348319872021 @default.
• W2034831987 crossrefType "journal-article" @default.
• W2034831987 hasAuthorship W2034831987A5000680390 @default.
• W2034831987 hasAuthorship W2034831987A5021530387 @default.
• W2034831987 hasAuthorship W2034831987A5026681457 @default.
• W2034831987 hasAuthorship W2034831987A5056152624 @default.
• W2034831987 hasAuthorship W2034831987A5068229812 @default.
• W2034831987 hasAuthorship W2034831987A5071471585 @default.
• W2034831987 hasAuthorship W2034831987A5077738215 @default.
• W2034831987 hasConcept C115260700 @default.
• W2034831987 hasConcept C121332964 @default.
• W2034831987 hasConcept C145148216 @default.
• W2034831987 hasConcept C155355069 @default.
• W2034831987 hasConcept C16889073 @default.
• W2034831987 hasConcept C178790620 @default.
• W2034831987 hasConcept C179104552 @default.
• W2034831987 hasConcept C185592680 @default.
• W2034831987 hasConcept C197162081 @default.
• W2034831987 hasConcept C198091228 @default.
• W2034831987 hasConcept C23792430 @default.
• W2034831987 hasConcept C26873012 @default.
• W2034831987 hasConcept C2777706827 @default.
• W2034831987 hasConcept C2780534640 @default.
• W2034831987 hasConcept C32546565 @default.
• W2034831987 hasConcept C32938098 @default.
• W2034831987 hasConcept C62520636 @default.
• W2034831987 hasConcept C73922627 @default.
• W2034831987 hasConcept C8010536 @default.
• W2034831987 hasConceptScore W2034831987C115260700 @default.
• W2034831987 hasConceptScore W2034831987C121332964 @default.
• W2034831987 hasConceptScore W2034831987C145148216 @default.
• W2034831987 hasConceptScore W2034831987C155355069 @default.
• W2034831987 hasConceptScore W2034831987C16889073 @default.
• W2034831987 hasConceptScore W2034831987C178790620 @default.
• W2034831987 hasConceptScore W2034831987C179104552 @default.
• W2034831987 hasConceptScore W2034831987C185592680 @default.
• W2034831987 hasConceptScore W2034831987C197162081 @default.

• next