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- W2034836710 abstract "Reactions of bis(isonitrosoethylacetoacetato)palladium(II), Pd(IEAA)2, with straight chain non-bulky alkylamines, RNH2(R = CH3, C2H5, n-C3H7 or n-C4H9) in the mole ratio 1:1 gave bis (B-alkyl isonitrosoethylacetoacetateimino)Palladium(II), Pd(R-IEAI)2. In this reaction the coordinated carbonyl groups of Pd(IEAA)2 undergo condensation with amines forming Schiff bases (>CNR). On the other hand, the reactions of Pd(IEAA)2 with a large excess of amine yielded N-alkylamido bridged isonitrosoethylacetoacetatedipalladium(II), μ-(NHR)2[Pd(IEAA)]2 complexes. The complexes are characterized by elemental analyses, magnetic susceptibility, i.r., p.m.r. and in some cases, nitrogen 1s X-ray photoelectron and mass spectral studies. Reaktionen des Bis(isonitrosoäthylacetoacetato)palladium(II) mit geradkettigen primären Aminen. Einfluß der Konzentration der Amine auf die Natur der Produkte Reaktionen des Bis(isonitrosoäthylacetoacetato)palladium(II), Pd(IEAA)2, mit geradkettigen, nichtsperrigen Alkylaminen, RNH2 (R = CH3, C2H5, n–C3H7 oder n-C4H9) im Molverhältis 1:1 ergaben Bis(N-alkyl-isonitrosoäthylacetoacetatimino)palladium(II), Pd(R-IEAI)2. Bei dieser Reaktion erfolgt über die koordinierten Carbonylgruppen des Pd(IEAA)2 Kondensation mit den Aminen unter Bildung Schiffscher Basen(>CNR). Andererseits ergibt ein großer Überschuß des Amins N-Alkylamido-verbrückte Isonitrosoäthylacetoacetatdipalladium(II)-Komplexe, μ-(NHR)2[Pd(IEAA)]2. Die Komplexe werden charakterisiert durch Elementaranalyse, magnetische, IR- und ESR-Messungen sowie in einigen Fällen durch N1s-Röntgen-Photoelektronen- und Massenspektroskopie." @default.
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- W2034836710 date "1978-09-01" @default.
- W2034836710 modified "2023-09-23" @default.
- W2034836710 title "Reactions of bis(isonitrosoethylacetoacetato)palladium(II) with straight chain aliphatic primary amines influence of concentration of the reacting amines on the nature of the products" @default.
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- W2034836710 doi "https://doi.org/10.1002/zaac.19784440126" @default.
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