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- W2034849797 abstract "Arylation and alkenylation of aromatic aldehydes with silanediols is shown to proceed by use of a catalytic amount of rhodium complex. Treatment of ethyl(4-methoxyphenyl)silanediol with benzaldehyde in the presence of 3 mol% of [Rh(OH)(cod)] 2 affords 4-methoxyphenyl(phenyl)methanol in 59% yield after stirring at 70 °C for 24 hours. On the other hand, diarylketone was also obtained at elevated temperature via β-hydride elimination from intermediary rhodium alkoxide." @default.
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- W2034849797 date "2010-05-21" @default.
- W2034849797 modified "2023-09-27" @default.
- W2034849797 title "ChemInform Abstract: Rhodium-Catalyzed Addition of Aryl- and Alkenylsilanediols to Aldehydes." @default.
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- W2034849797 doi "https://doi.org/10.1002/chin.200225049" @default.
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