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• W2034854821 abstract "Abstract Optical properties of nanocrystalline Nd-modified lead–zirconate–titanate thin films were studied. Pulsed laser deposition was used for thin-film fabrication at room temperature. Thin films were deposited on single-crystal MgO (100) substrates and post-annealed between temperatures 400 °C–1000 °C. The crystal structure and thin film morphology were studied using x-ray diffraction technique and atomic force microscopy, respectively. The optical transmission spectra of the films were measured at UV–vis–IR wavelengths and the results were utilized to obtain the refraction index n , extinction coefficient k , and the value of the band gap E g . Thin films annealed at different temperatures had a different crystal structure and morphology. Film thickness and annealing temperature also had an effect on the crystal orientation of the films. Trigonal and tetragonal phases co-existed in analyzed films so that films with thickness of 150 nm had strong tetragonal orientation with increasing post-annealing temperature. Trigonal and tetragonal phase co-existence was present in films with thickness of 300 nm post-annealed at low temperatures. Optical absorption edge shifted to shorter wavelengths with decreasing film thickness and post-annealing temperature which led to increase in band gap energies. Atomic force microscopy studies showed a clear dependence of films root mean square roughness on post-annealing temperature and crystal structure." @default.
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• W2034854821 date "2008-07-01" @default.
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• W2034854821 title "Effect of microstructure and surface morphology evolution on optical properties of Nd-modified Pb(ZrxTi1−x)O3 thin films" @default.
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• W2034854821 doi "https://doi.org/10.1016/j.tsf.2008.02.046" @default.
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