FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034856687> ?p ?o ?g. }

• W2034856687 endingPage "814" @default.
• W2034856687 startingPage "810" @default.
• W2034856687 abstract "Luminescence efficiency of lanthanide complexes generally largely depend on the choice of the organic ligand and the host matrix in which these complexes are doped. Two Sm(III) complexes, namely: Sm(III) dithicarbamate - Sm(L1)3B [L1=(R)2NCS2B, R=C2H5 and B=1,10-phenanthroline] and Sm(III) complex with the polytonic ligand L2=N', N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]ethanedihydrazide {Sm2-L2-(CH3COO)2; L2=C16H16N6O2} are synthesized, these complexes are then trapped in sol-gel glass. Room temperature luminescence of Sm(L1)3B and {Sm2-L2-(CH3COO)2} complexes encapsulated in sol-gel glass are studied using a spectrofluorometer. Up on excitation by a UV light, ligand L1B absorbs this light and transfers it into the Sm(III) ions and emission bands were observed in the visible region and were attributed to f-f transitions of Sm(III). The observed emission indicated an efficient L1B ligand as a sensitizer, while ligand L2 shows no ability to work as a sensitizer. The branching ratio I4G5/2→6H9/2/I4G5/2→6H7/2) of electric dipole transition to magnetic dipole transition was used as an effective spectroscopic probe to predict symmetry of the site in which Sm(III) is located. The encapsulation of the Samaium complexes was performed for three reasons: (i) before rare earth (RE)-doped sol-gel glasses can be used in applications such as laser materials, several fluorescence quenching mechanisms must be overcome, we show in this work that lanthanide fluorescence is greatly enhanced by chelation and selecting a suitable host matrix (sol-gel) to accommodate the lanthanide complex, (ii) to improve the stability of the phosphor with efficient and high color-purity characteristics under ultraviolet excitation and (iii) this work provides a framework for preparing transparent composite glasses that are robust hosts to study the fundamental interactions between nano-materials and light." @default.
• W2034856687 created "2016-06-24" @default.
• W2034856687 creator A5015213240 @default.
• W2034856687 creator A5062868993 @default.
• W2034856687 creator A5073437882 @default.
• W2034856687 creator A5085536045 @default.
• W2034856687 date "2013-11-01" @default.
• W2034856687 modified "2023-09-26" @default.
• W2034856687 title "Synthesis and luminescence properties of encapsulated sol–gel glass samarium complexes" @default.
• W2034856687 cites W1845771290 @default.
• W2034856687 cites W1964023518 @default.
• W2034856687 cites W1968762055 @default.
• W2034856687 cites W1969137131 @default.
• W2034856687 cites W1970803380 @default.
• W2034856687 cites W1978556711 @default.
• W2034856687 cites W1980618941 @default.
• W2034856687 cites W1981611739 @default.
• W2034856687 cites W1982052310 @default.
• W2034856687 cites W1985062662 @default.
• W2034856687 cites W1986219881 @default.
• W2034856687 cites W1988369794 @default.
• W2034856687 cites W1989928077 @default.
• W2034856687 cites W2000121493 @default.
• W2034856687 cites W2002307191 @default.
• W2034856687 cites W2005913958 @default.
• W2034856687 cites W2006192414 @default.
• W2034856687 cites W2010995463 @default.
• W2034856687 cites W2015581546 @default.
• W2034856687 cites W2017177049 @default.
• W2034856687 cites W2025369658 @default.
• W2034856687 cites W2035549360 @default.
• W2034856687 cites W2035758227 @default.
• W2034856687 cites W2043022830 @default.
• W2034856687 cites W2050767659 @default.
• W2034856687 cites W2053404311 @default.
• W2034856687 cites W2060277591 @default.
• W2034856687 cites W2060377704 @default.
• W2034856687 cites W2061040716 @default.
• W2034856687 cites W2061092612 @default.
• W2034856687 cites W2082998892 @default.
• W2034856687 cites W2091756227 @default.
• W2034856687 cites W2093210271 @default.
• W2034856687 cites W2097717011 @default.
• W2034856687 cites W2098477283 @default.
• W2034856687 cites W2126534026 @default.
• W2034856687 cites W2133372001 @default.
• W2034856687 cites W2133429098 @default.
• W2034856687 cites W2135865474 @default.
• W2034856687 cites W2142466588 @default.
• W2034856687 cites W2149063817 @default.
• W2034856687 cites W2151859760 @default.
• W2034856687 cites W2153589691 @default.
• W2034856687 cites W270091629 @default.
• W2034856687 cites W1970761318 @default.
• W2034856687 doi "https://doi.org/10.1016/j.saa.2013.06.109" @default.
• W2034856687 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23892122" @default.
• W2034856687 hasPublicationYear "2013" @default.
• W2034856687 type Work @default.
• W2034856687 sameAs 2034856687 @default.
• W2034856687 citedByCount "2" @default.
• W2034856687 countsByYear W20348566872015 @default.
• W2034856687 countsByYear W20348566872016 @default.
• W2034856687 crossrefType "journal-article" @default.
• W2034856687 hasAuthorship W2034856687A5015213240 @default.
• W2034856687 hasAuthorship W2034856687A5062868993 @default.
• W2034856687 hasAuthorship W2034856687A5073437882 @default.
• W2034856687 hasAuthorship W2034856687A5085536045 @default.
• W2034856687 hasConcept C113196181 @default.
• W2034856687 hasConcept C116569031 @default.
• W2034856687 hasConcept C120665830 @default.
• W2034856687 hasConcept C121332964 @default.
• W2034856687 hasConcept C122865956 @default.
• W2034856687 hasConcept C145148216 @default.
• W2034856687 hasConcept C148869448 @default.
• W2034856687 hasConcept C159985019 @default.
• W2034856687 hasConcept C169852918 @default.
• W2034856687 hasConcept C170493617 @default.
• W2034856687 hasConcept C171250308 @default.
• W2034856687 hasConcept C173523689 @default.
• W2034856687 hasConcept C178790620 @default.
• W2034856687 hasConcept C179104552 @default.
• W2034856687 hasConcept C185592680 @default.
• W2034856687 hasConcept C192562407 @default.
• W2034856687 hasConcept C197404232 @default.
• W2034856687 hasConcept C201770740 @default.
• W2034856687 hasConcept C203187862 @default.
• W2034856687 hasConcept C38398224 @default.
• W2034856687 hasConcept C49040817 @default.
• W2034856687 hasConcept C521977710 @default.
• W2034856687 hasConcept C536819264 @default.
• W2034856687 hasConcept C55493867 @default.
• W2034856687 hasConcept C57863236 @default.
• W2034856687 hasConcept C75473681 @default.
• W2034856687 hasConcept C91881484 @default.
• W2034856687 hasConceptScore W2034856687C113196181 @default.
• W2034856687 hasConceptScore W2034856687C116569031 @default.
• W2034856687 hasConceptScore W2034856687C120665830 @default.
• W2034856687 hasConceptScore W2034856687C121332964 @default.

• next