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- W2034859986 abstract "The effects of molecular exchange between two immiscible fluid phases are of considerable importance when interpreting N.M.R. lineshapes and relaxation times in systems such as emulsions or coacervates, but have not been fully explored theoretically. In general the nuclei in each phase must be considered as belonging to distinct chemical species which are interchanged by chemical reaction localized at the interface between the two fluids. By solving the Bloch-Torrey equations with new generalized boundary conditions describing this localized interfacial reaction we show how the N.M.R. spectral lineshape and relaxation times depend on the morphology of the system as well as on the rates of diffusion and interfacial reaction. Our results differ fundamentally from the traditional phenomenological description of exchange based on the Bloch-McConnell or Zimmerman-Brittin equations which take no explicit account of these factors. In order to illustrate these differences exact analytical solutions are derived for the simplest geometry where the two phases are lamellar. More complicated geometries can be treated by numerical methods." @default.
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- W2034859986 date "1988-10-10" @default.
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- W2034859986 title "The effects of exchange and interfacial reaction in two-phase systems on N.M.R. lineshapes and relaxation processes" @default.
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- W2034859986 doi "https://doi.org/10.1080/00268978800101051" @default.
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