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- W2034862829 abstract "Abstract In previous work measurements have been made of the excess osmotic pressure of sterically stabilized latices in dodecane. The stabilizing moieties, which were chemically linked to a core particle of poly(methylmethacrylate), were poly(12-hydroxystearic acid) chains, the latter chains extending into the dodecane. Measurements were made as a function of the volume fraction of the cores. Using both a Monte Carlo procedure and a cell model, theoretical computations have now been made of the osmotic pressure as a function of volume fraction and the calculations compared with the experimental results. The model was based on a pair potential for the particle-particle interaction which took account of the thickness of the steric stabilizing layer and the interaction of the solvent with the stabilizing chains. Good agreement can be obtained between theory and experiment particularly if the polydispersity of the stabilizing chains is taken into account." @default.
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- W2034862829 date "1981-02-01" @default.
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- W2034862829 title "A comparison between theoretically computed and experimentally measured pressures for interacting sterically stabilized particles" @default.
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- W2034862829 doi "https://doi.org/10.1016/0021-9797(81)90102-8" @default.
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