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• W2034871982 abstract "We have combined the techniques of 13C nuclear magnetic resonance (n.m.r.) and nitric acid degradation to obtain information on the location of the side chains in branches polyethylene. Surprisingly, we have found that the ethyl and butyl groups are mainly excluded from the crystalline zones. The longer branches can cocrystallize with the main chain. Knowledge of the numbers and types of branch in polymers is of some technological important in polymer science. Short chain branching has a marked effect on the mechanical properties of the polymer, whilst the long chain branching affects the properties of melts." @default.
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• W2034871982 date "1977-10-01" @default.
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• W2034871982 title "Chain branching in high pressure polymerized polyethylene" @default.
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• W2034871982 doi "https://doi.org/10.1016/0032-3861(77)90003-9" @default.
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