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• W2034872568 startingPage "134" @default.
• W2034872568 abstract "Reaction of the potassium salts of RC(S)NHP(S)(OiPr)2 (R = MeNH, HLI; iPrNH, HLII; tBuNH, HLIII; Me2N, HLIV; PhNH, HLV; 2,6-Me2C6H3NH, HLVI; 2,4,6-Me3C6H2NH, HLVII) with [Cu(PPh3)3I] or a mixture of CuI and Ph2P(CH2)nPPh2 (n = 1, 2, 3) in aqueous EtOH/CH2Cl2 leads to mononuclear 1–6, 8–10, 12–27 or binuclear 7, 11 complexes. The structures of these compounds were investigated by 1H, 31P{1H} NMR spectroscopy and elemental anayses. The crystal structures of 1, 2, 4, 5, 11, 18, 20 and 21 were determined by single crystal X-ray diffraction. The luminescence properties of mononuclear complexes 1, 21, 22 and 27, and binuclear complexes 7 and 11·C3H6O are reported." @default.
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• W2034872568 date "2010-01-01" @default.
• W2034872568 modified "2023-09-25" @default.
• W2034872568 title "Copper(I) complexes with N-thiophosphorylated thioureas and phosphines with versatile structures and luminescence" @default.
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• W2034872568 doi "https://doi.org/10.1039/b914163d" @default.
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